Explain bromination of n-n-dimethylaniline, Chemistry

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Explain Bromination of N-N-dimethylaniline

Bromination of N,N-dimethylaniline is faster because nitrogen has an unshared electron pair that can stabilize the carbocation intermediate by resonance. As in the case of oxygen, the electron-withdrawing polar effect of nitrogen is much less significant than its electron-donating resonance effect.

 


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