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Bolter:
(kE2 - kE1) = 0, (pE2 - pE1) = 0, w1-2 = 0
Now, q1-2 = w1-2 (h2 - h1) + (kE2 - kE1) + (pE2 - pE1)
q1-2 = h2 - h1
Heat supplied in boiler increases the enthalpy of system.
q1-2 = w1-2 (h2 - h1) + (kE2 - kE1) + PE2 - pE1) - q1-2 = h2 - h1
Heat energy is lost by the system to the cooling water
q1-2 = h1 - h2
Essence of Second Law: Sol: First law deals with conservation and conversion of energy. But it fails to state the conditions under which the energy conversion are possible.
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