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Cis-1,3-di-tert-butylcyclohexane can exist in a chair conformation (A) in which both tert-butyl groups are equatorial. Though, in either chair conformation of trans-1,3-di-tert-butylcyclohexane (B), there is an axial tert-butyl group. The axial tert-butyl group can be avoided if compound B exists in a twist-boat conformation C. in which both tert-butyl groups are equatorial. Evidently the twist-boat conformation is more stable than either chair conformation having an axial tert-butyl group. The interaction of the methyl groups with the ring hydrogens should be about the similar in both conformations A and C, so that these cancel in the comparison.
In the study of mechanisms of various chemical reactions, Deuterium and Tritium are used as tracers.
Which of the following is not true in Rutherford's nuclear model of atom: (1) Protons and neutrons are present inside nucleus (2) Volume of nucleus is very small as compared
Thats a hypothesis and Yes it becomes a string.
What is Tube extrusion Billet is placed inside a container between die and mandel. Mandel is pressed by ram and metal is extruded through the die. This process is used for m
Calculate the combustion energies for the burning of 1 mol of propane and butane. It can be supposed that all reactants and products are obtained under standard conditions.
Q. Explain about Stereoisomerism? Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometri
Q. Explain Preservation by Preservatives? Preservatives, as you may already know, belong to a class of food additives that extend shelf life by inhibiting microbial growth, o
Classify each reaction and give the name of all the chemical formula involved for each number. 1. Na2CO3(s) + SiO2(s) ? Na2SiO3(l) + CO2(g) 2. 2 Mg(NO3)2(s) ? 2 Mg(NO2)2(s) + O2
explain the bonding and structure in transition metal carbonyls
give an assignment of organic compounds
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