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Cis-1,3-di-tert-butylcyclohexane can exist in a chair conformation (A) in which both tert-butyl groups are equatorial. Though, in either chair conformation of trans-1,3-di-tert-butylcyclohexane (B), there is an axial tert-butyl group. The axial tert-butyl group can be avoided if compound B exists in a twist-boat conformation C. in which both tert-butyl groups are equatorial. Evidently the twist-boat conformation is more stable than either chair conformation having an axial tert-butyl group. The interaction of the methyl groups with the ring hydrogens should be about the similar in both conformations A and C, so that these cancel in the comparison.
Average life of a radioelement is the characteristics property of the element. Explain
High ionisation energy: The high ionisation energy of helium (24.6 eV) makes it a potential gas to be used in plasma source. The nitrogen gas is generally not used as a pla
Name a substance which on addition to AgCl causes vacation vacancy in it. Mention a large scale use of the phenomenon called 'reverse osmosis'.
Fission of Covalent bond
Explain the Three Liquids - Ternary Phase Diagram? Figure on the next page is the ternary phase diagram of a system of ethanol, benzene, and water at a temperature and pressure
Phenol (Carbolic acid), C 6 H 5 OH or Hydroxy benzene It was observed by Runge in the middle oil fraction of coal-tar distillation and termed it 'carbolic acid' (carbo = coal, o
why f elememnts kept sepertaly in periodic table
Carboxylate salts Carboxylate salts are less reactive than esters in nucleophilic acyl substitution reactions for two reasons. First, resonance stabilization of carboxylate s
Evaporation theory and describe advantages, disadvantages and application?
Complexes of actinides
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