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Cis-1,3-di-tert-butylcyclohexane can exist in a chair conformation (A) in which both tert-butyl groups are equatorial. Though, in either chair conformation of trans-1,3-di-tert-butylcyclohexane (B), there is an axial tert-butyl group. The axial tert-butyl group can be avoided if compound B exists in a twist-boat conformation C. in which both tert-butyl groups are equatorial. Evidently the twist-boat conformation is more stable than either chair conformation having an axial tert-butyl group. The interaction of the methyl groups with the ring hydrogens should be about the similar in both conformations A and C, so that these cancel in the comparison.
Chain Lengthening of Aldoses (Killiani-Fischer synthesis) The conversion of an aldose to the next higher member includes the subsequent steps : (a) Creation of a cyanohydrin
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Q. What is Alloys? Metals have a property of combining with other metals to form alloys. An alloy may be defined as a solid which is formed by a combination of two or more met
can all the total heat content available betotally converted to work done?
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Q. How can we obtain Boron? Boron is- obtained by the red-action of B 2 O 3 with magnesium or sodium B 2 0 3 is first prepared by strongly katingH 3 B0 3 which is obtained b
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