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Cis-1,3-di-tert-butylcyclohexane can exist in a chair conformation (A) in which both tert-butyl groups are equatorial. Though, in either chair conformation of trans-1,3-di-tert-butylcyclohexane (B), there is an axial tert-butyl group. The axial tert-butyl group can be avoided if compound B exists in a twist-boat conformation C. in which both tert-butyl groups are equatorial. Evidently the twist-boat conformation is more stable than either chair conformation having an axial tert-butyl group. The interaction of the methyl groups with the ring hydrogens should be about the similar in both conformations A and C, so that these cancel in the comparison.
why is electron gain enthalpy of oxygen greater than sulphur?
OUTLINE AND EXPLAIN THE LIMITATIONS OF VBT
Draw the important resonance contributors for the benzenoium intermediate in the bromination of aniline and explain why ortho, para substitution predominates ?
What are the most significant properties of permanent magnetic materials? Explain. Ans: The most significant properties of permanent magnetic materials are (i) Remanen
Properties of Catechol 1. Catechol is a colourless crystalline solid, its melting points is 105°C. 2. Catechol is soluble in water. 3. Catechol is exaggerated on exposure
GROUP 2: ALKALINE EARTHS The elements known commonly as alkaline earths have atoms with the (ns) 2 design and almost always have the +2 oxidation state in their compound
what is the acidity of phenol?
How can you find the formula for a specific ion?
whats a reversible cell
Q. Determine Equilibrium Constants for Acid and base? Ans. The pH scale of acidity is a simple and convenient way to state the acidity of a solution. The
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