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Q. Show diffrent type of Ligands?
Ligands which contain one donor atom are called monodentate the donor atom may contain
One or more than one lone pairs of electrons. The ligands that contain two, three, four and so on donor atoms are called bidentate, tridentate. tetradentate etc., respectively. For example, .NH3, H20, F- are all monodentate ligands: CO2-3, SO2-4, H2NCH2COOH (glycine) are all bidentate ligands. Table 14.1 gives a list of anions/molecules commonly used as ligands.
A bidentate ligand like ethylenediamine is a neutral molecule but a glycinate ion, H2NCH2COO-, which is not neutral can also act as a bidentate ligand. The nitrogen atom and one of the oxygen atoms of glycinate ion can form chemical bonds with a metal ion. In order to differentiate a ligand like glycinate we call it a bidentatemo no negative ligand.
The boron trihalides are highly volatile; BF 3 (b. p., 173 K) and BCI 3 , (b. p., 260.5 K are gases, BBr 3 a volatile liquid (b. p., 319 K) and Bl 3 a low melting solid (m. p.,
what is the stability order of Li2, H2, B2 B.O of Li2 is 1 B.O of H2 is 1 B.O of B2 is also 1 so for stability order u need to see the no of electrons in antibonding orbitals mo
Applications of Photochemistry
Direction of the shift of electron pair The direction of the shift of electron pair can be decided on the basis of subsequent points. (i) While the sets related to a multipl
Equilibria Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for
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What is sublimation?
A gas is a fluid. It has no resistance to change of shape and will expand indefinitely to fill any container in which is held. The molecules or atoms which make up a gas interact o
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