Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Q. Illustrate Born-Haber cycle?
Boron is always covalent and does not form,B3+ ions, because' the energy required to remove three electrons is very high. Many simple compounds of A1 and Ga like AlCl3 and GaCl3 are also covalent when anhydrous. However, in solution, the large amount of hydration energy evolved compensates the high ionisation energy and all the' metal ions exist in a hydrated state.
This can be explained with the help of Born-Haber cycle as given below. However, this is a simplified approach given only on the bas; of enthalpy changes, whereas the direction and extent of any reaction depend on the free energy changes which take into account changes both in enthalpy and entropy.
Thus, despite the large ionisation energies of aluminium, the enthalpy of' solution of AlCl3 has a large negative value. Therefore, in aqueous solution, AIC3 exists as AI3+(aq) and Cl-(aq). It might be thought that the same argument would apply to BCI3; But to make the enthalpy of solution of BCl3 nethalpy the enthalpy of hydration of B3+ should be - 6009 KJ which is unlikely for the small B3+cation. Therefore, BC13 hydrolyses in aqueous solution to give boric acid and not B3+ (aq).
BCl3 + 3H20 -----------------------------------> H3B03 + 3HCI
verirification of law of chemical combination
Which geometry does have Formaldehyde molecule The formaldehyde molecule has trigonal planar geometry. Therefore, both the H-C-H bond angle and the H-CAO bond angle are abou
The spectrum of He is expected to be similar to: (1) H (2) Li + (3) Na (4) He + Ans: Li +
Q. Illustrate Aromatics compounds? Ans. Benzene (C 6 H 6 ) is the prototype of an important class of hydrocarbons called aromatic compounds. Benzene is a ring of 6 carbon
What isbrutherford contribution to thr eludication of atomic structurr
which is more acidic among o-methoxy benzoic acid and m-methoxy benzoic acid Ans) O-methoxy benzoic acid is more acidic than m-metoxy benzoic acid.
Q. Determine the peroxide value in the of fat? After undertaking this activity, you will be able to: • determine the peroxide value in a given sample of fats/oils, and •
Fine grain sizes are obtained by slow cooling
Nylone–66 is formed by
dehydration of alcohol with mechanism
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd