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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
which is more acidic among o-methoxy benzoic acid and m-methoxy benzoic acid Ans) o-methoxy benzoic acid is more acidic than m-metoxy benzoic acid.
give 2 examples of compounds that are bonded in the following ways (a) Hydrogen bonding (b)Vander waal forces (c) Co-ordinate covalent bonding. Explain with the aid of diagram how
For liquids - Drying of Organic Substances Organic liquids are usually dried by keeping them over night in contact along with a dehydrating (desiccating) agent that does not re
What methods can I use to understand balancing equations?
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Condensation reaction of carbonyl compounds Nucleophilic addition reaction of compounds comprising carbonyl group along with those compounds that have at least one acidic hydro
which element have highest oxidation number and why?
the reaction of kmno4 nd c2o4 .why does it produce brown colour first
Polarity and salvation A solvent is a liquid medium in which dissolved are known as solutes. Solvents are useful for storing species that would otherwise be in inconvenien
Q. General Characteristics of elements of Group 13? All the elements of Group 13 have similar valence shell electronic configuration of ns 2 np 1 , but the underlying core vari
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