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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
define hardness and its types.
WHAT IS THE IUPAC NAME OF K4[FeO4]
Composition of protein - Biomolecules Composition of a protein changes with source. An estimated composition is as follows: Carbon from 50-53%; hydrogen from 6-7%; oxygen fr
Carboxylate salts Carboxylate salts are less reactive than esters in nucleophilic acyl substitution reactions for two reasons. First, resonance stabilization of carboxylate s
what is oxidation state?
Although fractose does not have an aldehydic group, it reacts with Fehling solution Explain why? Ans) Fructose is a ketone first we cnvert it into aldehyde by reacting fructse
Effect of substituent on acidic nature (a) An electron withdrawing substituent that is - I effect stabilizes the anion by dispersing the negative charge and hence increases the
why sio doesn''t exist under normal conditions
Acetic Acid or Ethanoic Acid Acetic acid is the oldest termed as fatty acid. It is the major constituent of vinegar and therefore its name (Latin acetum = vinegar)
Why 2-methyl propanal gives canizzaro Rex.
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