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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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give 2 examples of compounds that are bonded in the following ways (a) Hydrogen bonding (b)Vander waal forces (c) Co-ordinate covalent bonding. Explain with the aid of diagram how
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1s 2 , 2s 2 , 2p 6 3s 1 shows configuration of: (1) Al 3+ in ground state (2) Ne in excited state (3) Mg + in excited state (4) None of these Ans: Mg + in
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how many number of electrons are possible in the valence shell of metals
The maximum energy is present in any electron at: (1) Nucleus (2) Ground state (3) First excited state (4) Infinite distance from the nucleus Ans: Infinite dis
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During a titration with EDTA, using eriochrome black T as indicator to determine Ca 2+ , an analyst obtained the following volumes of EDTA in three different trials: 5.01, 4.93 an
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