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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
The difference among Threshold energy and average energy of the molecules is known as activation energy.
which kind Acid &Basic radical present in this?
A hydrocarbon z with molecular mass 78 on combustion gave 3.384g of carbon (IV) oxide and 0.693g of water. Determine the molecular formula of Z and draw its structure. [H=1, C=12,
Dihydric alcohols - Hydrocarbon These are compound consisting of two hydroxyl sets. These are dihydroxy components of alkanes. Their common formula is A n H 2n+2 O 2 . The very
Complexes
How do you account for the following: (a) All scandium salts are white. (At. No. of Sc = 21) (b) The first ionization energies of the 5d transition elements are higher than
In the following which substance will have highest boiling point: (1) He (2) CsF (3) NH 3 (4) CHCl 3 Ans: CsF
programming
The quantum number which specifies the location of an electron as well as energy is : (1) Principal quantum number (2) Azimuthal quantum number (3) Spin quantum number
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