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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
can all the total heat content available betotally converted to work done?
The freezing point of ethylene glycol is -3.2 degree-Celcius. How many grams of ethylene glycol is required in 150 L of water to achieve such temperature?
principles of GCMS
what is meant by 100% current efficiency in electrogravimetry
What is the electronic configuration of Cu 2+ (Z= 29) of least position: (1) [Ar]4s 1 3d 8 (2) [Ar]4s 2 , 3d 10 4p 1 (3) [Ar]4s 1 3d 10
When an egg is boiled, the proteins present inside the egg get denatured and coagulate. After boiling the egg, the water present in it is absorbed by the coagulated protein through
Simple proteins Simple proteins are made up of chains of amino acid units just joined by peptide linkages. These types of proteins on hydrolysis yield just only mixture of amin
what does ammonia gas and chloride mixed, make?
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Q. Show the Colour of actinides and lanthanides Ions? Ions of actinides and lanthanides are coloured in the solid state as well as in aqueous solution, as is the case with the
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