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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
This of the following is an electrovalent linkage: (1) CH 4 (2) MgCl 2 (3) SiCl 4 (4) BF 3 Ans: MgCl
what is sludge and scale formation describe
A 100 gal tank contains 10 lb of water. The tank is filled by two inlet streams, one of pure water and one of pure ethanol. The flow rate of both streams is 10 gal/min. Calculate t
How can explain it
what is stereomerism
17.4g CaCO3= mol O
why are aromatic nitro compounds pale yellow in colour
i) Define a membrane in a process engineering context. Two of the main desired attributes of membranes are high permeability and high selectivity. Define permeability and select
How many unpaired electrons are present in Ni 2+ cation (atomic number = 28): (1) 0 (2) 2 (3) 4 (4) 6 Ans: 2
Can we vary the pressure while phases remain in equilibrium? Consider a system containing only NH 4 Cl(s), NH 3 (g), and HCl(g). Assume that the equilibrium NH 4 Cl(s) ↔ NH
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