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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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Illustrate and demonstrate that, for correct mass balance, relative amount of two co-existing phases or micro constituents should be as given by lever rule. The lever rule giv
discuss the dietary functional properties of calcium in foods
p-orbitals of an atom in presence of magnetic field are: (1) Two fold degenerate (2) Non degenerate (3) Three fold degenerate (4) None of these Ans: Non degenerate
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Q. Define Taste sensitivity? The concentration of a substance (in saliva) required to trigger the sensation of taste is much higher than the concentration of a substance (in ai
seawater contains 0.75g of Fe+3 per kilogram of water. What is the concentration of Fe_3 in ppm?
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