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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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Q. Consider the combustion of methane: Suppose the reaction occurs in a flowing gas mixture of methane and air. Assume that the pressure is constant at 1 bar, the reactant
#question.reactions of s-block element?.
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What will be de-Broglie wavelength of an electron moving with a velocity of 1.2 x 10 5 ms -1 : (1) 6.068x 10 -9 (2) 3.133 x 10 -37 (3) 6.626x 10 -9
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Classification of polymers - Elastomers The polymers which have elastic character such as rubber (a material that can return to its unique shape after stretching is said to be
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