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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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Q. How can we obtain Pure alumina? Pure alumina is obtained from bauxite ore. Powdered bauxite mineral is heated in a concentrated solution of sodium hydroxide under pressure w
Determine about the silicate clays The silicate clays develop charges because of an imbalance which takes place due to an exchange of one cation by the other in the crystal str
Alkanes have single bond, but why are they less reactive as compared to alkenes or alkynes which have respectively double or triple bonds ? Alkanes have only single sigma bond w
Electron configurations are governed by a limitation called as the Pauli Exclusion Principle: No two electrons can have the same value for all four quantum numbers n, l, m a
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