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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
what is the principal of radiometric titration
calculate the electrode potential of a platinum electrode immersed in a solution containing Ce4 + ions (cCe4 + = 0.05M) and Ce3 + ions (cCe3 + = 0.1M)
Give one significant use of each of the following: (i) Bithional (ii) Chloramphenicol (iii) Streptomycin (iv) Paracetamol
Enthalpy, H, is defined by the relationship H=U+pV. The enthalpy change, ΔH, for finite changes at constant pressure is given by the expression ΔH = ΔU+pΔV, so making the enthalpy
explain diffusion
When sodium and chlorine reacts then: (1) Energy is released and ionic bond is formed (2) Energy is released and a covalent bond is formed (3) Energy is absorbed and ioni
State the function along with one example each of: (i) Antihistamines (ii) Antioxidants (b) What are hybrid propellants?
potentiometric titration
if the electon in hydrogen atom is exited to n=5 the number of diffrent frequency of radiations which may be exited is
describe iron exchange process
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