Explain cycloaddition reaction, Chemistry

Assignment Help:

This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other.  Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition.  The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process.  In either case, the product has the following stereochemistry:

 

827_chemistry.png


Related Discussions:- Explain cycloaddition reaction

Bohr''s model of the hydrogen atom, Which of the following statements does ...

Which of the following statements does not form part of Bohr's model of the hydrogen atom: (1) Energy of the electrons in the orbit is quantized (2) The electron in the orbi

Cid, what is acid

what is acid

Dicarboxylic acids, Dicarboxylic acids The acids consisting of two carb...

Dicarboxylic acids The acids consisting of two carboxylic groups are known as dicarboxylic acids. The saturated dicarboxylic acid are denoted by the general formula 2n (COOH

What are total variables and degrees of freedom of a system, What are total...

What are total variables and degrees of freedom of a system of two components, when the number of phases is one, two, three etc.?  Ans:  For two - component systems, degree of

Inorganic, what is diagonal relationship in periodic table

what is diagonal relationship in periodic table

What are the interfacial defects, What are the Interfacial Defects  Gra...

What are the Interfacial Defects  Grain boundaries are interfaces where crystals of dissimilar orientations meet. A grain boundary is a single-phase interface, with crystals on

Reaction, how analysis of iodine value

how analysis of iodine value

Sodium, what can be formed by sodium reacting with epsum salt

what can be formed by sodium reacting with epsum salt

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd