Explain cycloaddition reaction, Chemistry

Assignment Help:

This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other.  Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition.  The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process.  In either case, the product has the following stereochemistry:

 

827_chemistry.png


Related Discussions:- Explain cycloaddition reaction

Fluid behaviour , A diluted polymer solution with a density of 1130 kg/m3 w...

A diluted polymer solution with a density of 1130 kg/m3 was extruded by a capillary tube of 3.5 mm internal diameter and 1 m long.  The following results were contained at 25°C.

Which of the sub-shell is circular, Which of the sub-shell is circular: ...

Which of the sub-shell is circular: (1) 4s                      (2) 4f         (3)  4p                 (4) 4d Ans: 4s

Neutrons than protons at high mass numbers because, Nuclei tend to have mor...

Nuclei tend to have more neutrons than protons at high mass numbers because: (1) Neutrons are neutral particles   (2) Neutrons have more mass than protons   (3) More neut

Moles, when 100ml of M/10 H2S04 is mixed with 500ml of M/10 NaOH then natur...

when 100ml of M/10 H2S04 is mixed with 500ml of M/10 NaOH then nature of resulting solution and normality of excess of reactant left isum 100 words accepted#

Classification of carbon molecules in organic compounds, Classification of ...

Classification of carbon molecules in organic compounds The carbon atoms in an alkane molecule may be categorized into four types namely Primary (1 o ), Secondary (2 o ),

Water treatment, how to know which salt causes scale formation and which on...

how to know which salt causes scale formation and which one for sludge formation

Isomerism - organic chemistry, Isomerism - Organic Chemistry Organic su...

Isomerism - Organic Chemistry Organic substance comprising the same molecular reaction but differing from each other at least in some physical or chemical properties or both ar

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd