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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Mechanism of reduction (b)
Describe this blocking by drawing the interaction between water and the catalyst analogous to that of task 1 of this problem. If a metal catalyzes the hydrogenation of alk
Determine the density of cesium chloride which crystallises in bcc type structure with the edge length 412.1 pm.The atomic masses of Cs & Cl are 133 & 35.5 respectively. Solution
why they have low electronegativity?
IR of nitro compound
project
suppose n mmol of solute A in Vaq ml of aqueous solution is extracted with Vorg ml of animmiscible organic solvent. at equilibrium n1 mmol of A will remain in the aqueous layer and
(i) Use valence shell electron pair repulsion theory (VSEPR) to predict the shape of the molecule comprising oxygen, nitrogen and fluorine atoms, which has the formula ONF, and whe
how is a peptide bond made through dehydration, showing a complete chemical equation
d orbital
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