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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Applications of hybridisation - Size of the hybrid orbitals As s- orbitals are closer to the nucleus than p- orbitals, it is reasonable to suppose that greater the s character
Pyroligneous acid - Aldehydes and Ketones Pyroligneous acid consisting of acetic acid, acetone and methyl alcohol that is distilled in copper vessel and the vapours are passed
What is the diagonal relationship between Beryllium and Aluminium
Classification of proteins - Conjugated proteins The molecules of conjugated proteins are made up of simple proteins and non protein material. The non-protein material is known
Fractional crystallisation- Purification of organic compound The method of separation of diverse components of a mixture by repeated crystallisations is termed as fractional cr
trend of atomic size
alkali metals belong to s-block in the periodic table.why?
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Although cholrine is electoon withdrawing group.yet it is ortho nd para directing in electrophilic aromatic substitution reactants.why? Ans) Halogens are an exception of the dea
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