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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
experiment with diagram
The hydration of propene The hydration of propene includes the usual mechanistic steps of alkene protonation to form a carbocation followed by the nucleophilic reaction of wate
Acidic nature of monocarboxylic acids (1) Cause of acidic nature (a) A atom of carboxylic acid may be illustrated as a resonance hybrid of the following structures.
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100 mol/hr pentane flows through an adiabatic heat exchanger where it is heated isobarically (at 2.5 bar) from 50°C to 250°C. The pentane is heated by contacting pipes filled with
the application of intervase
what is the liquid metal
Express the relation among the half-life period of a reactant and its initial concentration if the reaction involved is of second order. How are formalin and trioxane related to
what are the application of law of chemical combination?
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