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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Why +ve P.F. gives nuclear instability where as -ve PF gives nuclear stability ?explain .
Sensory evaluation during product life cycle The basic procedure for developing a new product, and supporting it while marketed, included distinct steps that are constant no
Q. At 298.15K, the partial molar volume of CO 2 (aq) is 33cm 3 mol -1 . Estimate the percent change in the value of the Henry's law constant kH,B for aqueous CO 2 at 298.15K when
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I want an Assignment about mechanism and techniques of polymerization
Write the reactions and the conditions involved in the conversion of: a. Propene to 1-Propanol b. Phenol to Salicyclic acid
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