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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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why ionisation energy of aluminium is greater then Ga?
DISAVANTAGES OF FLAME AAS
In order to determine the standard electrode potential of an electrode, the electrode in standard conditions is connected to standard hydrogen electrode (SHE) to constitute a cell.
explain galvanic potentiol differnce
A water treatment plant is to process 30,000 m3/d of raw water. A tapered flocculation basin having four flocculators with velocity gradients 40/sec, 30/sec, 20/sec and 10/sec is t
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Q. Consider the lime-kiln process CaCO 3 (s) -> CaO (s) + CO2 (g). Find the number of intensive variables that can be varied independently in the equilibrium system under the foll
Stereochemical arrangement has an issue whenever an atom is bonded to two or more others. Thus triatomic substance AB2 can be bent or linear. It is observed that when a central ato
Uses of Alkyl nitrites (1) Ethyl nitrite dialates the blood vessels and so accelerates pulse rate and lowers blood pressure thus it is utilized for a medicine for the treatment
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