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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
I HAVE TO PREPARE A ASSIGNMENT ON LIQUID CRYSTAL. AND I WANT TO MAKE IT DIFFERENT FROM OTHER, ACTUALLY I GOT THE MATTER FROM OUR BOOK BUT OUR TEACHER SAID THAT YOU DON''T HAVE TO C
Certain basic properties of lakes and oceans are important to understanding how they "work". One of these is the density of the water, and its changes. Dense (or heavier) water wan
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Give chemical reaction in support of each of the following statements: (i) The +1 oxidation state gets stabilised progressively from Ga to TI in Group (ii) All the bonds PCl5
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energy order of octahedral, tetrahdral, squareplaner.
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