Explain cycloaddition reaction, Chemistry

Assignment Help:

This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other.  Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition.  The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process.  In either case, the product has the following stereochemistry:

 

827_chemistry.png


Related Discussions:- Explain cycloaddition reaction

Nitrocompounds, nitroalkane sare acidic in nature.Explain

nitroalkane sare acidic in nature.Explain

Organic, total metal in word

total metal in word

Diaper rash alternative, RL, a 28-year old first time father, was watching ...

RL, a 28-year old first time father, was watching his 4-month old baby for the weekend while his wife was away at a sales meeting. Things were going well. He had run out of breast-

Physical properties of phthalic acid, Physical properties of Phthalic Acid ...

Physical properties of Phthalic Acid  (a) Phthalic acid is colourless crystalline substance. (b) Phthalic acid's melting point is not sharp (195-213°C). (c) Phthalic acid

Bohr''s model can explain, Bohr's model can explain : (1) The spectrum o...

Bohr's model can explain : (1) The spectrum of hydrogen atom only    (2) Spectrum of atom or ion containing one electron only  (3) The spectrum of hydrogen molecule  (4

What is the rate constant for a reaction of zero order, The rate constant f...

The rate constant for a reaction of Zero order in A is 0.0030 mol L¯¹ s¯¹. How long will it take for the initial concentration of A to fall from 0.10 M to 0.075 M?

State the term - ferrites, State the term - Ferrites Ferrites are used ...

State the term - Ferrites Ferrites are used as ferromagnetic materials for high frequency applications like TV tubes, memory devices, high-speed switches, microwave application

The two electrons in k sub-shell will differ in, The two electrons in K sub...

The two electrons in K sub-shell will differ in : (1)Principal quantum number (2)Azimuthal quantum number (3)Magnetic quantum number (4)Spin quantum number Ans:Spin

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd