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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
The two chair conformations of cis-1,3-dimethylcyclohexane
PFEFFER METHOD
Q. Show Multiplying Quantities Written in Scientific Notation? Multiplying Quantities Written in Scientific Notation Solve the following problem. (2 * 10 14 cm) * (9 *
group1 metal reacts execess of oxygen
Physical properties of Adipic Acid (a) Adipic Acid is a white crystalline solid. Its melting point is 150°C. (b) Adipic Acid is fairly soluble in alcohol and ether but less
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Chemical properties of monohydric alcohols Characteristic reaction of alcohol are the reaction of the - OH group. The reactions of the hydroxyl group includes either cleavage o
biography on Cecil E Boord
Distinguish between van''t Hoff Method and Oswald Isolation Method. In each case give an expression for the rate of reaction.
verify the law of multiple proportions for an element X, which forms oxides having percentages of X equal to 77.4%, 63.2%,69.6% and 72.0%
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