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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Which type of compounds show high melting and boiling points: (1) Electrovalent compounds (2) Covalent compounds (3) Coordinate compounds (4) All the three types of co
Q. Write an account of soda lime glass and safety glasses. Ans. Soda-Lime Glass or soft glass: It is the ordinary glass in which Na 2 O is added to the melt to oxide on hea
1. The temperature of the warm water bath is recorded too high. How will this technique error affect the reported activation energy for the reaction - too high or too low? explain
Electrons and nuclei The familiar planetary model of the atom was proposed by Rutherford in 1912 following experiments by Geiger and Marsden showing that all the mass of an
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Which of the following is ideal for Oxidation of propene to propan-1-ol a)Alkaline KMnO 4 b)B 2 H 6 /Alkaline KMnO 4 c)O 3 /Zn dust d)CrO 3 Ans) B 2 H 6 /Alkaline KMno4 is th
1. Air is available at 70°F and humidity of 0.001lb/lb. It is to be treated to yield 130°F and 70% humidity. Offer a reasonable design. 2. A mix of granular ceramic
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