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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
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Properties of Styrene Styrene is a colourless liquid, boiling point 145°C. On keeping, it slowly changes into a solid polymer known as meta styrene. The polymerisation is fast
0.22(6.022)(10^23)
The gas stream from a sulfur burner is composed of 15-mol% SO 2 , 20-mol% O 2 , and 65-mol% N 2 . This gas stream at 1 bar and 680°C enters a catalytic converter, where the SO 2
The hybradization state of the Fe among [Fe(CN)6]3-,[Fe(CO)5] and [Fe(H2O)6]2+ is Ans) D2SP3,DSP3,SP3D2
Determine the molality of an aqueous solution that is 12.0 percent urea by mass
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