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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
metal A was determined to be 95%extracted into methylene chloride with dethizone at pH6, when equal volumes of aqueous and non-aqueous solvents were used. what is the distribution
Consider 1:1 stoichiometric polymerisation of 1, 4-diaminobutane with sebacoyl chloride. (a) Write down a balanced chemical equation for the polymerization (b) Name the polym
describe the steps necessary in preparing a standard solution of 1.0 molar NaOH
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Which of the following set of quantum number is not possible: n l m1 m2 (a) 3 2 1
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In a potassium atom, electronic energy levels are in the following order: (1) 4s>3d (2) 4s>4p (3) 4s (4) 4s Ans: 4s
what is the working principle of potentiometry
On mixing acetone and chloroform, a reduction in total volume occurs. What kind of deviations from ideal behavior for solutions is given in this case and why?
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