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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Correct statement is: (1) K=4s 1 , Cr= 3d 4 4s 2 , Cu= 3d 10 4s 2 (2) K=4s 2, Cr= 3d 4 4s 2 , Cu= 3d 10 4s 2 (3) K=4s 2 Cr= 3d 5 4s 1 , Cu= 3d 10
The covalency of nitrogen in HNO 3 is: (1) 0 (2) 3 (3) 4 (4) 5 Ans: 5
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CARBON, SILICON AND GERMANIUM With the valence electron configuration s 2 p 2 the nonmetallic group of elements 14 may form compounds with four tetrahedrally directed covalent
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Question: (a) Explain why metals are mostly ductile and ceramics brittle at room temperature. (b) Describe what you understand by the following terms. Use appropriate il
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