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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Q. Show the Chemical property of matter? A chemical property explains the ability of a substance to combine with or change into one or more other substances. For instance the
Q. Show the rate of decrease in atomic radius? The rate of decrease in atomic radius along the lanthanide series and also along the actinide series is even less than that in th
2NO(g)+2H2O yeilds N2+2H2O Write the rate law for the pervious reaction if doubling the concentration of H2 doubles the reaction rate, and if doubling the concentration of NO incre
Voltammetry: You learnt about voltammetry. Several electrodes, especially the general microelectrodes used in voltammetry were discussed. Then we discussed the common voltamme
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What is the electronic configuration of Cu 2+ (Z= 29) of least position: (1) [Ar]4s 1 3d 8 (2) [Ar]4s 2 , 3d 10 4p 1 (3) [Ar]4s 1 3d 10
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Explain the two peaks in the diagram. How can a living cell control the position of the second peak to adapt the properties of its membrane to the demands of life? In blood, li
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