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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
Uses of Oxalic acid or Polyprotic acid (i) Oxalic acid is used in the manufacture of carbon monoxide, formic acid and allyl alcohol. (b) Oxalic acid is used as a laboratory
the uses,preparation,and the reaction
Reaction of conjugate addition This reaction is a "conjugate addition" of cyanide ion on a cyclopropane. Notice that reaction at the least branched carbon of the cyclopropane
types of electrochemical cells any 5
The amount of heat liberated when single mole of any substance is completely burnt in oxygen is known as heat of combustion H is negative for heat of combustion.
why is carbon valency four
how to plot van der waals equation of state with surface discontinouity in python programming language
Q. Explain about Dihalide? Dihalides: Dichlorides and dibromides are formed by the lower members of the group, viz., Se, Te and Po. These are formed mainly by dissociation of t
Classification of Carboxylic acids (a) Carboxylic acids are categorized as dicarboxylic acids, tricarboxylic acids and monocarboxylic acids etc. depending upon the number of -
Write conditions and reactions for the following conversions: (i) Chloroform into diethylcarbonate (ii) Phenol into salicylic acid (iii) 2-propanone into 2-inethyl-2-prop
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