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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
give an clear explanation about kohlrauschs law
Q. Illustrate Kinetic Molecular Theory of Gases? Ans. The behavior and properties of gases can be explained by the Kinetic Molecular Theory (KMT). A gas that behaves accord
A substance that has a molecular structure built up chiefly or completely from a large number of similar units bonded together.
The total number of electrons present in all the p-orbitals of bromine are: (1) Five (2) Eighteen (3) Seventeen (4) Thirty five Ans: Seve
Nitro alkanes and alkyl nitries (preparation and properties)
Q. Show reversible and exothermic reaction? The fact that SO 2 , can be oxidised to SO 3 , by air in the presence of platinum catalyst is the basis of the contact process which
In electrochemical series moving down the table the ease of discharge at cathode increases.why? And what is ease of discharge
markonise and anti markonise
What is chemical and physical properties and uses of acid halides and acid anhydrides
why is density of interstitial compounds less than that of parent metal ?
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