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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s] cycloaddition. The heptafulvene molecule is large enough that its p-electron system can twist without introducing too much strain or without losing too much p-electron overlap; hence, the cycloaddition is a [14a + 2s] process. In either case, the product has the following stereochemistry:
When 100ml of M/10 h2so4 is mixed with 500 ml of M/10 naoh then nature of resulting solution and normality of excess of reatant left is 1)Acidic,N/5 2)basic ,N/5 3)Acidic,N/20 3)ac
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Krypton ( 36 Kr) has the electronic configuration (18 Ar) 4s 2 , 3d 10 , 4p 6 . The 37 electron will go into which one of the following sub-levels: (1) 4f
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Free radical replacement reactions Free radical substitution reactions include the attack by a free radical. These reactions happen by free radical mechanism that includes Init
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