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Q. Explain about Optical Isomerism?
Optical Isomerism: -Two isomers which have almost identical physical and chemical properties like mp. B p. density. Colour etc.. But differ in the way they rotate the plane-polarised light are called optical isomers. Such optically active compounds exist in pairs and are known as stereoisomers or enantiomers. These isomers are non-super imposable mirror images of each other. Hence any molecule which contains either a-centre of symmetry or a plane of symmetry will not show optical isomerism.
Optical isomerism is rarely observed in square planar complexes. Tetrahedral complexes of the type [M(AB)2] do give optical isomers as shown in Fig, especially where / M = Be, B etc.
However optical isomerism very common with octahedral complexes of the type! M (AA)3. M(AA)2ab, M(AA)a2,b2. M(AA)(BB)a2 etc. A few typical examples.
Q. Show diffrent type of Ligands? Ligands which contain one donor atom are called monodentate the donor atom may contain One or more than one lone pairs of electrons. The l
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