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Dichromate titrations - oxidation reduction titrations
These are titrations where, potassium dichromate is utilized as an oxidising agent in acidic medium. The medium is organized acidic by the make use of dilute sulphuric acid. The potential reaction is
K2Cr2O7 + 4h2SO4 → K2SO4 + Cr2 (SO4)3 + 4 H20 + 3[O]
OR Cr2 O2-7 + 14 H+ + 6e- → 2 CR3+ + 7 H2O
The solution of potassium dichromate can be directly employed for titrations. It is generally used for the estimation of ferrous salts and iodides. In the titration of K2Cr2O7 versus ferrous salt either an external indicator that is potassium ferricyanide or an internal indicator that is diphenyl amine can be used.
Calculate the free energy change of following reaction at298 kelvin H2+I2=2HI if the enthalpy change is 51.8816kj and the entropy change is 166.15j is this reaction thermodyanamica
diagram
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DRAW A SET UP FOR THE FOLLOWING SEPERATION TECHNIQUES; FILTRATION,SEPERATING FUNNEL EVAPORATION ,DECANTATIOON, DISTILLATION.
give three examples with good details
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