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An ozone, O3, sparger system has been proposed for a water-treatment plant. The incoming water in a 80 m3 pond has been stripped of all ozone-demanding substances, and the pH is sufficiently low such that the ozone decomposition will be insignificant. The ozone bubbler will have eight spargers, each using a compressed gas feed containing 4 mol % ozone. The spargers will be located 3.2 m below the surface of the pond and each sparger's gas rate will be 17.8 m3 /h. Henry's law constant for the ozone-water system will be 0.0677 atm/(mol/m3 )
a. Use the Eckenfelder plot for oxygen transfer factor, kL(A/V), and evaluate the kL(A/V) for ozone, recalling that the penetration theory predicts, for mass transfer from gas bubbles into liquids, that kL(A/V) will be proportional to the liquid diffusivity raised to the power of 1/2. The diffusivity of oxygen in water is 2:14 × 10-5 cm2/s and the diffusivity of ozone into water is 1:7 × 10-5 cm2/s.
b. Determine the time required to raise the initially ozone-free water in the pond to a concentration level of 0.15 mol/m3.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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