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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
Atoms in the water molecule are linked by: (1) Electrovalent bond (2)Covalent bond (3) Coordinate covalent bond (4) Odd electron bond Ans: Cov
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#questionWHY LANE''S PROCESS IS ALSO KNOWN AS VIVIFICATION PROCESS?..
The correct ground state electronic configuration of chromium atom is: (1) [Ar] 3d 5 4s 1 (2)[Ar]3d 4 4s 2 (3) [AR]3d 6 4s 0 (4
Law of equivalence - Volumetric analysis The Law of equivalence is applied in all volumetric estimations. As per to it, the chemical substances react in the ratio of their
Fe+ AgNO3-->Fe(NO3)2 + Ag
Is it the key or the lock of the lock and key model? Ans) The activation center is a region of the enzyme formed by its spatial conformation to which the substrate binds. In the
What will happen if you mix nitrogen and hydrogen gas at room temperature? Explain your reasoning. Calculate the mole fraction of NH 3 that would form theoretically at 298.15
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