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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
ENTROPY Entropy is a thermodynamic property of a system. It is denoted as S and like as the enthalpy and internal energy, it is a state function. In thermodynamic expression, e
Streptomycin: It was discovered in the year 1944 by Waksman. Streptomycin is successful against tuberculosis. It is as well used for other general infections such as ears, thro
Difference between Natural rubber and Vulcanized Rubber Natural rubber Vulcanized rubber (1) it is soft and sticky Vulcanized
Physical properties of Phenol (a) Phenol is a colorless crystalline, deliquescent solid. It attains pink colour on exposure to air and light. (b) Phenol is capable of formin
reasons of failure
The ground state term symbol for an electronic state is governed by : (1) Heisenberg's principle (2) Hund's rule (3) Aufbau principle (4) Pauli exclusion principle
name any 10 chemical compound used at homewith their molecular formula
fe is a non stoichiometric compound
Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a primary alkyl halide and undergo SN2 rapidly.
Could you please provide me the priority order of polyfunctional prefixes
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