Why octahedral complexes of ni+2 must be outer orbitals?, Chemistry

Assignment Help:

The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization  and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN-  ion forming

[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.


Related Discussions:- Why octahedral complexes of ni+2 must be outer orbitals?

Entropy and second and third law of thermodynamics, ENTROPY Entropy is ...

ENTROPY Entropy is a thermodynamic property of a system. It is denoted as S and like as the enthalpy and internal energy, it is a state function. In thermodynamic expression, e

Streptomycin - drugs and medicines, Streptomycin: It was discovered in ...

Streptomycin: It was discovered in the year 1944 by Waksman. Streptomycin is successful against tuberculosis. It is as well used for other general infections such as ears, thro

Difference between natural rubber and vulcanized rubber, Difference between...

Difference between Natural rubber and Vulcanized Rubber Natural rubber Vulcanized rubber  (1) it is soft and sticky Vulcanized

Physical properties of phenol, Physical properties of Phenol (a) Phenol...

Physical properties of Phenol (a) Phenol is a colorless crystalline, deliquescent solid. It attains pink colour on exposure to air and light. (b) Phenol is capable of formin

The ground state term symbol for an electronic state, The ground state term...

The ground state term symbol for an electronic state is governed by : (1) Heisenberg's principle  (2) Hund's rule (3) Aufbau principle (4) Pauli exclusion principle

Matter, name any 10 chemical compound used at homewith their molecular form...

name any 10 chemical compound used at homewith their molecular formula

Benzylic halide undergo sn1 or sn2 mechanism , Will benzylic halide undergo...

Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a  primary alkyl halide and undergo SN2 rapidly.

IUPAC Naming, Could you please provide me the priority order of polyfunctio...

Could you please provide me the priority order of polyfunctional prefixes

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd