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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
why cerium oxides is less soluble in water?
Q. Define atomic mass units? Atomic mass Scientists have set up a standard for the measurement of atomic mass by assigning the carbon-12 atom a mass of 12 atomic mass units (a
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Q. How many degrees of freedom has a system consisting of solid NaCl in equilibrium with an aqueous phase containing H 2 O, NaC(aq), Cl (aq), HC(aq), and OH (aq)? Would it be possi
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Acceptance tests What are Acceptance Tests? Acceptance tests are used to evaluate product acceptability or liking or to determine which of a series of products is the most acc
The quantum number which specifies the location of an electron as well as energy is : (1) Principal quantum number (2) Azimuthal quantum number (3) Spin quantum number
During a titration with EDTA, using eriochrome black T as indicator to determine Ca 2+ , an analyst obtained the following volumes of EDTA in three different trials: 5.01, 4.93 an
The maximum number of electrons that can be accommodated in the M th shell is: (1) 2 (2) 8 (3) 18 (4) 32 Ans: 18
WhT is pollymara
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