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The coordination number of Ni in the complex is 4, the configuration of Ni+2 , at first sight, shows that the complex is formed by sp 3 hybridization and it is paramagnetic and it has two unpaired electrons. However, experiments show that the complex is diamagnetic, i.e. it do not have unpaired electrons, this is possible when 3d electrons rearrange against the hund's rule as shown in the below configuration. This is also in accordance with the fact that the ligand involved here is a strong i.e. CN- ion.Hence now dsp2 hybridization, involving one 3d, one 4s and two 4p orbitals, takes place leading to four dsp2 hybrid orbitals, each of which accepts four electron pairs from CN- ion forming
[Ni (CN4)] 2 ion. Thus the resulting complex is square planar and is diamagnetic as it has no unpaired electrons.
sodium does not react with a) Carbon b) Nitrogen c) Hydrogen d)both a an b
Few methods preparation of cyacloalken
Classify phylum protozoa upto classes giving characters and suitable examples.
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why do soap not work in hard water ?
Neoprene (GR: or Polychloroprene or Dupe) Preparation: Neoprene is prepared by the free radical polymerisation of chloroprene in an emulsion system. Starting materials are ac
Q. Write an account of soda lime glass and safety glasses. Ans. Soda-Lime Glass or soft glass: It is the ordinary glass in which Na 2 O is added to the melt to oxide on hea
Q. Explain Basic physical properties of Gas? Ans. Gases are the least dense phase of matter. Gases can be easily expanded or compressed. They exert pressure equally in
meaning of laws of chemical
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