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The model of trans-bicyclo decane
The model of trans-bicyclo[5.3.0]decane is easier to build. The larger is a ring, the easier it is to compress the dihedral angle of the trans bonds at the ring junction without introducing significant strain in the ring. This angle must be very close to 0° in order to accommodate a fused cyclopropane, that is, to bridge the ends of trans bonds with only one carbon.
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CRYSTAL FIELD THEORY
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