Which set of quantum numbers are not possible, Chemistry

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Which set of quantum numbers are not possible from the following:

(1) n=3, l= 2, m=0, s= -1/2

(2) n=3, l= 2, m=-2 s= -1/2

(3) n=3, l= 3, m=-3, s= -1/2

(4) n=3, l= 0, m=0, s= -1/2

Ans: n=3, l= 3, m=-3, s= -1/2

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