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Some important types of electrodes which are frequently used in electrochemical cells are described as follows:
Metal-metal ion electrode: such type of electrodes includes a metal rod dipped in the solution of its own ions. Some examples areZn/Zn2+, Ag/Ag+, Cu/Cu+ etc. Amalgam electrodes: these are similar to metal-metal ion electrodes, but here the metal is used in the form of its amalgam with hg. Amalgam is formed to modify the activity of metal. (An-Hg)/Zn2+ is one of the common examples of this type. Gas electrodes: such electrodes involve inert metal such as platinum dipped in the solution containing ions of the gaseous element. The arrangement is made in such a manner that gas and its ions are brought in contact at the surface of the inert metal. Some examples along with their electrode reactions are as follows: Hydrogen electrode : Pt, H2(g)/H+(aq) H2 2H+ + 2e- or 2H+ + 2e- H2 Chloride electrode : Pt, Cl2(g)/Cl-(aq) 2Cl- Cl2 + 2e- or Cl2 + 2e- 2Cl- Bromine electrode : Pt, Br2(g)/Br-(aq) 2Br- 2Br2 + 2e- or Br2 + 2e- 2Br- Metal-metal insoluble salt-salt anion: in such electrodes, the metal and some sparingly soluble salt of metal are dipped in aqueous solution of some other soluble salt whose anion is same as that of sparingly soluble salt of the metal. One of the common examples is Ag-AgCl(s)/KCl(aq). Here, silver and sparingly soluble salt of Ag, i.e. AgCl is put in aqueous solution of KCl. The concentration of Ag+ions in KCl solution is controlled from the knowledge of Ksp of AgCl as follows. The electrode reactions are as follows: Ag(s) + Cl-(aq) AgCl + e- oxidization AgCl(s) + e- Ag(s) + Cl-(aq) reduction Another important example of this type of electrode is calomel electrode: Hg-Hg2Cl2(s)/KCl(aq), whose electrode reactions are: 2Hg(l) + 2Cl-(aq) Hg2Cl2(s) + 2e- oxidization Hg2Cl2(s) + 2e- 2Hg(l) + 2Cl-(aq) reduction Redox electrodes: these electrodes include a platinum wire dipped in a solution of a mixture of two salts of the same metal having different oxidation states. Some ordinary examples are listed below: Pt, Fe2+/Fe2+ Fe2+ Fe2+ + e- Or, Fe2+ + e- Fe2+ Pt, Sn2+/Sn4+ Sn2+ Sn4+ + e- Or, Sn4+ + 2e- Sn2+
Radioactive decay is a process whereby unstable nuclei change into more stable nuclei by emitting particles of different kinds. Alpha, beta and gamma (α, β and γ) radiation was cla
Approximate the torque and power necessary to rotate the inner 20 cm diameter cylinder shown in Figure 1. SAE 10W-30 oil at 20°C fills the gap. Assume a linear velocity profile.
1. CH2=CH-CH3 inpresence of SO2Cl2 (UV light) product..?? 2. (CH3)3CH +Cl2 undergo photo halogenation product..?? 3. 1-propyne react with HCl product is? Solution) 1 SO2Cl2 resu
Which one of the following is not the characteristic of Planck's quantum theory of radiation: (1)The energy is not absorbed or emitted in whole number or multiple of quantum
Draw the important resonance contributors for the benzenoium intermediate in the bromination of aniline and explain why ortho, para substitution predominates ?
If the value of azimuthal quantum number is 3, the possible values of magnetic quantum number would be: (1) 0, 1, 2, 3 (2) 0, - 1, - 2, - 3 (3) 0 ± 1± 2,± 3
mechanism for the enzyme-catalyzed
Electrovalent compounds are: (1) Good conductor of electricity (2) Polar in nature (3) Low M.P. and low B.P. (4) Easily available Ans: Polar in nature
wat are d limitations of octet rule...??
Ask qhow chemical eqlibrium establish uestion #Minimum 100 words accepted#
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