State differences between primitive cells and unit cells, Chemistry

Assignment Help:

What are similarities and differences of primitive cells and unit cells? 

Ans:  Unit  cell  is  the  basic  building  block  of  a  crystal,  repeated  infinitely  in  three dimensions.

It's characterized by the three vectors (a, b, c) that form edges of a parallelopiped and the angles between the vectors (alpha, angle between b and c; beta, the angle between a and c; gamma, angle between a and b).

A primitive cell is a unit cell built on the basis vectors of a primitive basis of direct lattice, namely a crystallographic basis of the vector lattice L such that each lattice vector t of L may be obtained as an integral linear combination of basis vectors, a,  b,  c. It comprise only one lattice point and its volume is equal to the triple scalar product (a, b, c).

Non-primitive bases are used usually to illustrate centered lattices. In that case, unit cell is a multiple cell and it contains more than one lattice point. Multiplicity of the cell is given by the ratio of its volume to volume of a primitive cell.

 


Related Discussions:- State differences between primitive cells and unit cells

Dextrorotary compounds and levi rotary compounds, What are dextrorotary com...

What are dextrorotary compounds and Levi rotary compounds? Ans) Compounds that rotate the plane polarized light to the right are known as Dextro rotatory compounds and that rota

Edta method, explain the principle of EDTA method

explain the principle of EDTA method

Titration of hcl with standard sodium carbonate solution, how do you calcul...

how do you calculate the concentration of hcl solution if you are the mass of sodium carbonate and the volume of its solution and the volume of the pipetted solution and the volume

Idoform, preparation of idoform

preparation of idoform

Periodic table, what groups comprise each block of elements(s,p.d and f blo...

what groups comprise each block of elements(s,p.d and f blocks)in the periodic table

The amino acid glutamine , The amino acid glutamine can be produced bythe f...

The amino acid glutamine can be produced bythe following equilibrium in the presence of a suitable catalyst.  The equilibrium constant for this reaction is 3.5 x 10-3 at 25 oC.

Assingment, introduction of chemical bond

introduction of chemical bond

Buffers, how do you prepare 100mM pH 7.4 of Potassium phospate buffer

how do you prepare 100mM pH 7.4 of Potassium phospate buffer

Stoichiometry, if 45.0 L of natural gas, which is essentially methane, unde...

if 45.0 L of natural gas, which is essentially methane, undergoes complete combustion at 730 mm Hg and 20 degrees Celsius, how many grams of each product are formed?

What does thermodynamics helps in predicting, Predicting the feasibility of...

Predicting the feasibility of reaction and does not show the rate of chemical reaction

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd