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A student attempting to sulfonate styrene (vinyl benzene) obtains a by product that contains neither sulfur nor oxygen atoms. Efforts to nitrate styrene yield identical results. Of the 2 diastereomers of this product identified by GC, one is crystallized and characterized. Its IR spectrum features prominent bands at 3050, 2950, 1615, and 1500 cm-1, and its 1H and 13C NMR spectra are summarized below. Identify the product, assign its NMR and IR signals to the corresponding protons and bonds, and propose a mechanism for its formation. (You do not need to determine or explain the stereo chemical configuration.)
The process of chromatography involves passing a mixture dissolved in the "mobile phase" through a stationary phase, which separates the analyte which is to be measured from the ot
One mole of gas A decomposed exothermically into one mole of gas B and one mole of gas C with Kp = 1.8 x 10-5 at 300 K. If the initial pressure of each gas was 0.150 atm, what were
Explain Cyclobutane Cyclobutane undergoes an interconversion of puckered forms analogous to the chair interconversion of cyclohexane. This interchanges axial and equatorial gr
Which of the following sets of quantum numbers is not allowed : (1) n=1, l=0,m=0 s= +1/2 (2) n=1, l=1,m=0 s= -1/2 (3) n=2, l=1,m=1 s= +1/2
Mechanism of reduction (b)
the value of plank''s constant
advantages of reversible reaction
Ortho, meta and para 1. Ortho (or 1, 2-) : if the two substituents are on the adjacent carbon atoms, the compound is said to be ortho (or 1, 2-). 2. Meta (or 1, 3-) : if the
What are the limitations of valence bond theory?
Which forms a crystal of Nacl: (1) Nacl molecules (2) Na + and cl - ions (3) Na andcl atoms (4) None of the above Ans: Na + and cl - ions
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