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Q. Illustrate about Werners Theory?
Based on the study of a large number of compounds. Wermer gave the following postulates:
• Metal atoms in complexes possess two types of valences namely. Principal or an auxiliary or secondary.
• Primary valencies are always satisfied by anions but the secondary valencies can be satisfied either by anions and/or neutral molecules.
• Every metal atom has a fixed number of auxiliary valencies.
The secondary valencies show directional properties. In other words secondary valencies are directed in space around the central ion.
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For principle quantum numbern= 4 the total number of orbitals having l=3: (1) 3 (2) 7 (3) 5 (4) 9 Ans: 7
The angle among the lines joining the nuclei of the bonded atom with a central atom is known as bond angle.
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