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Q. Illustrate about Werners Theory?
Based on the study of a large number of compounds. Wermer gave the following postulates:
• Metal atoms in complexes possess two types of valences namely. Principal or an auxiliary or secondary.
• Primary valencies are always satisfied by anions but the secondary valencies can be satisfied either by anions and/or neutral molecules.
• Every metal atom has a fixed number of auxiliary valencies.
The secondary valencies show directional properties. In other words secondary valencies are directed in space around the central ion.
In a Bohr's model of atom when an electron jumps from n= 1 to n= 3 , how much energy will be emitted or absorbed: (1) 2.15 x10 -11 erg (2) 0.19
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Reaction of conjugate addition This reaction is a "conjugate addition" of cyanide ion on a cyclopropane. Notice that reaction at the least branched carbon of the cyclopropane
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