Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

Equilibria, Equilibria Equilibrium can also exist in between the same s...

Equilibria Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for

A cyclic ester, The lactone, a cyclic ester, can form an enolate ion, and t...

The lactone, a cyclic ester, can form an enolate ion, and this ion is alkylated by methyl iodide.

Composition of individual phase in phase diagram–three phase, Define Compos...

Define Composition of individual phase in phase diagram–three phase? A binary system with three phases has only one degree of freedom and cannot be represented by an area on a

Benzaldehyde - aldehydes and ketones, Benzaldehyde - Aldehydes and Ketones ...

Benzaldehyde - Aldehydes and Ketones Benzaldehyde is simple aromatic aldehyde. It occurs in bitter almonds in the type of its glucoside, amygdalin (C 20 H 27 O 11 N). While amy

Boiler troubles and their consequences, Q. What are boiler troubles? Discus...

Q. What are boiler troubles? Discuss their consequences? Sol. Boiler feed water (water for steam making): water is very important engineering material which is mainly used fo

Describe the foaming properties, Q. Describe the foaming properties? Fo...

Q. Describe the foaming properties? Foods like meringue, ice cream and beer contain foams. A number of foods possess good foaming properties on account of the proteins they con

Sources of aliphatic hydrocarbon, Sources of aliphatic hydrocarbon Mine...

Sources of aliphatic hydrocarbon Mineral or crude oil, petroleum is the dark colour oily liquid along with offensive odour found at several depths in many regions below the sur

Avart sarni, Spurt tricks to learn avart sarni

Spurt tricks to learn avart sarni

Packing fraction, Why +ve P.F. gives nuclear instability where as -ve PF gi...

Why +ve P.F. gives nuclear instability where as -ve PF gives nuclear stability ?explain .

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd