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Entropy (S) is a molecular 'disorder', or more precisely 'the number of microscopic arrangements of energy possible in a macroscopic sample'. Entropy depends strongly on the state and increases with rise in temperature.
Entropy changes (ΔS) are positive for reactions that generate gas molecules. The Second Law of Thermodynamics defines that the total entropy always increases in a spontaneous process, and reaches a maximum value at equilibrium. To apply this to chemical reactions it is necessary to include entropy changes in the surroundings caused by heat output or input. Both external and internal changes are taken account of by defining the Gibbs free energy change (ΔG): for a reaction performing at constant temperature.
Prepare a table that lists the expressions for the dimensionless concentration profiles and catalyst effectiveness factors for slab, cylinder and spherical catalysts.
Quantitative analysis - Estimation of Elements After qualitative analysis of elements, the another step in the determination of molecular formula of an organic compound is
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A cylinder is equipped with a frictionless piston with an inner diameter of 5 cm and a mass of 3 kg. A 27 kg weight rests on the piston. One mole of helium at 25 o C fills the cyl
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The electronic configuration of a dipositive metal M 2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be: (1) 30 (2)32
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