Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

Homework help, seawater contains 0.75g of Fe+3 per kilogram of water. What ...

seawater contains 0.75g of Fe+3 per kilogram of water. What is the concentration of Fe_3 in ppm?

The ph scale, The pH scale: The equation: p Kw =14.00=pH+pOH is obtaine...

The pH scale: The equation: p Kw =14.00=pH+pOH is obtained by taking the negative logarithm to the base 10 of the autoprotolysis equation, where In general pX denotes -

Quantitative analysis, Quantitative analysis: The quantitative analysi...

Quantitative analysis: The quantitative analysis could be carried out using standard calibration curve, through standard addition or internal addition method. The method is su

For ns orbital, For ns  orbital, the magnetic quantum number has value: ...

For ns  orbital, the magnetic quantum number has value: (1) 2             (2) 4        (3) - 1               (4) 0 Ans:0

Periodic table, what groups comprise each block of elements(s,p.d and f blo...

what groups comprise each block of elements(s,p.d and f blocks)in the periodic table

What concentration of b alone is increased to three times, A reaction is of...

A reaction is of first order in reactant A and of second order in reactant B. How is the rate of this reaction affected when (i) the concentration of B alone is increased t

Acids, what acid would be added to limestone to form calcium chloride

what acid would be added to limestone to form calcium chloride

Basic radicals, Why lead and mercury are in 1st and 2nd group of basic radi...

Why lead and mercury are in 1st and 2nd group of basic radicals

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd