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(a) Derive a relationship between the elevation in boiling point of a solution and the mole fraction of the solute from the thermodynamic consideration.
(b) The molal elevation constant (Kb) and the boiling point for CCl4 are 5.02 deg/moll and 76.80C respectively. Calculate the boiling point of 1.0 molal solution of naphthalene in carbon tetrachloride. 2+3 = 5
Q. Draw a vapour pressure composition diagram for an ideal binary solution obeying this law and compare this with similar diagram showing derivation from Raoult's law. Why do these deviations occur?
Q. Draw a phase diagram for the CO2 system using the following data:
Solid CO2 (dry ice) sublimes at 1 bar pressure and -780C.The triple point is at 5.18bar and 56.60C.The critical point is at 74bar and 31.10C.The density of solid is 1.56 gml-1and that of liquid is 1.11gml-1 .The enthalpy of fusion is 8.34kjmol-1. 5
Q. Calculate the equilibrium constant for the reaction A+2B ---> C , if 1.0 moles of A ,2.0 moles of B and 3.0 moles of C are placed in a 1.0 dm3 vessel and allowed to come to equilibrium. The final concentration of C is 1.4 mol dm-3. 3
Q. Derive an expression for Gibb's Duhem Equation. How chemical potential varies with temperature and pressure?
determination of glucose,fructose and maltose.
priming and foaming define?
Why the current flow is always oppositte in direction to the conventional current direction? Ans) Availability of free electrons and application of potential difference are the c
Limitations of 3rd law
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Characteristics of homologous series (i) All the members of a series can be presented by the general formula. For instance, the members of the alcohol family are illustrated b
list the physical properties of two examples of metallic and non metallic elements
sodium prepration
Q. How to Replace Metals from their Salts: Ans. If zinc is added to a solution of copper (II) sulfate, it dissolves. A reddish-brown deposit of metallic copper appears,
how do I find an empirical formula?
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