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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
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Q. Uses of selenium? Uses of selenium include photocopying process of xerography, decobrisation of glasses and as a catalytic agent particularly in the isomerisation of certain
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On a hot summer day in July, Jennifer is trying to make Popsicles. If she is using 20.6 g of fruit juice how much heat is released when the Popsicle changes from liquid to solid a
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Just like lithium and beryllium in Groups Land 2, boron also shows anomalous behaviour. In general, the boron chemistry resembles that of silicon (occupying a diagonal position in
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