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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
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This of the following is an electrovalent linkage: (1) CH 4 (2) MgCl 2 (3) SiCl 4 (4) BF 3 Ans: MgCl
Q. Crystal Field Splitting in Octahedral Complexes? Let us consider an octahedral complex, ML6, where M is a metal ion and L stands for a ligand. The total charge on the comple
Is there a way to reverify alcoholic acidity using pH?
Bohr's model can explain : (1) The spectrum of hydrogen atom only (2) Spectrum of atom or ion containing one electron only (3) The spectrum of hydrogen molecule (4
Why 2-methyl propanal gives canizzaro Rex.
Physical properties of Phenol (a) Phenol is a colorless crystalline, deliquescent solid. It attains pink colour on exposure to air and light. (b) Phenol is capable of formin
a) Give a chemical test to distinguish between aniline and N-methyl aniline. Draw the structure of XeF2 molecule. b. Write the outer electronic configuration of Cr atom (Z =
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