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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
Explain The compound decarboxylates The compound decarboxylates; it is a disubstituted malonic acid in which the two a substituents are connected within a ring. The net effect
Applications of flame photometry: A few common applications of flame photometry are given below. Flame photometry could be used to detect the presence of the elements o
The boron trihalides are highly volatile; BF 3 (b. p., 173 K) and BCI 3 , (b. p., 260.5 K are gases, BBr 3 a volatile liquid (b. p., 319 K) and Bl 3 a low melting solid (m. p.,
Test Ethyl cyanide Ethyl isocyanide Smell Strong but pleasant Extremely unpleasant Dipole moment
Fractional distillation - Purification of organic compounds This method is used to separate a mixture of two or more miscible liquids that have boiling points close to each oth
redox reaction of ethanal,caustic soda&copper hydroxide
why do soap not work in hard water ?
?H value obtained for the reaction NH3 + HCl –› NH4Cl using the thermodynamic data in your lab procedure?
Uses of Aromatic Nitro Compounds (a) Aromatic Nitro Compounds are used on account of their high polarity, aromatic nitro compounds are used as solvents. (b) Nitro compounds
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