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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
formation of energy bonds in solids are in accordance to? give reasons .
what is the difference between both independent and dependent variables?
Q. What is Electronic Isomerism? Electronic Isomerism: The complex {Co (NH 3 )sNO]Cl 2 exists in two forms. One is black paramagnetic while the other is pink and diamagnetic
Typical conductometric titration curve for a weak aci and a strong base
Q. Explain about Thiosulphuric Acid? Thiosulphuric acid, H 2 S 2 0 3 , has never been isolated but its salts are well known which contain the thiosulphate ion, S 2 O 2- 3 . Th
Explain in detail about the thermal oxidation The following reactions take place during thermal oxidation: During oxidation, Si - SiO 2 interface moves into silicon. A
Use the VSEPR model to predict approximate molecular geometries and electron-domain for the following species. (a) XeF 2 , (b) NH3Cl + , (c) BrO2 -
Why it called p-block elements?
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