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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
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Nomenclature of Bicyclic compounds Several hydrocarbons and their derivatives include two fused or bridged rings. The carbon atoms are common to both rings are known as bridge
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Molten sodium chloride conducts electricity due to the presence of: (1) Free electrons (2) Free ions (3) Free molecules (4) Atoms of sodium and chlorine Ans: Free
1. (a) Reacting Pt 2+ with two equivalents of each of the ligands NO 2 - and en, it is possible to prepare several complexes that could be described as both geometric and opti
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