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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
P= 10.5atm v= 2.06L T= 298K p= 5.21atm v= 6.15 t= ? what is t?
give instrumentation of electrogravimetry
why the water is compound
In naturally occuring neon, the fracional abundance of various isotopes is as follows: 20Ne =0.9051; 21Ne = 0.0027; 22Ne = 0.0922. What is the atomic mass of neon?
Explain Carbocation The mechanism is a sequence of two Brønsted acid-base reactions. In the first (step a), the double bond is protonated to give a tertiary carbocation; in the
A Chloroplatinic of a diacid base contain 39% of platinum what is the molecular weight of the base
Q. Explain about coordination compound? These compounds are usually formed by the donation of pair of electrons to the central metal ion by the group of ions or molecules. The
What is meant by linear combination of atomic orbitals? State bonding and antibonding molecular orbitals based on bomo-nuclear dihydrogen molecule.
Q. Transition elements of the f-block? The salient features of the chemistry of the transition elements of the f-block. Due to filling of electrons in the f-orbitals of an inne
Amines are soluble in organic solvents whereas ammonium salts are not. Is it true? Ans) yes because amine is contain R-NH2 group where R is carbon groups so they are in polar nat
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