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The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limiting step.
A small effect of isotopic substitution occurs in this case because of the differential effect of deuterium and hydrogen on the rehybridization of carbon in the transition state. (The carbon bearing the deuteriums rehybridizes from sp2 to sp3 in the rate-limiting step.) However, this effect on rate amounts to only a few percent. Effects of this sort are called secondary deuterium isotope effects.
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what is the mechanism of acyl chloride reaction with alcohol and why does it react in this way ?
Explain propene In propene, the H 3 C-C bond dipole adds vectorially to the smaller H-C bond dipole; the resultant is smaller than the H 3 C-C bond dipole itself, as th
Nuclei contain uncharged neutrons and positively charged protons; these two particles with about the same mass are known as nucleons. The number of protons is the atomic number of
name and chemical formula of blue vitriol
1. In water softening, which of the precipitates will settle out? 2. For particle sizes larger than 1μ in size 3. In non-ideal type II settling 4.The most usually used me
what are the most important rules of iupac nomenclature that a student should know
Explain the Liquid junctions? Some galvanic cells contain two electrolyte solutions with different compositions. These solutions must be separated by a porous barrier or some o
Naming complex substituents - IUPAC system of nomenclature If the substituent on the parent chain is complex ( that is it is branched) it is termed as substituted alkyl g
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