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Q. Complexation Behaviour of the f-block?
Ions of actinide and lanthanide elements have a strong tendency to form complexes with a variety of oxygen and nitrogen donor ligands. Perhaps, because of their comparatively higher charge to size ratio, the actinide ions have a greater tendency to form complexes than the lanthanides. Also, because of the existence of a large number of oxidation states, the complexation behaviour of actinides is more varied. The lanthanide and actinide ions form the most stable complexes with chelating ligands such as oxalic acid, tartaric acid, citric acid, nitric acid, ethylenediamine tetraacetic acid (EDTA) and 0-diketones. In these complexes the metal ions have very high coordination numbers. For case, the coordination number of the metal ion in [Th(acac)4]. [Ce(N03)4.(OPPh3)2] and [Ce(N03)6]2- is 8, 10, 12, respectively. In these complexes, the acetyl acetonate (acac) and the nitrate ligands are operating as bidentate ligands occupying two coordination sites around the metal ion. These metal ions form water soluble complexes with citric acid, tartaric acid and EDTA. The formation of water soluble complexes with these ligands facilitates separation of the metal ions by ion exchange chromatography.
Pb(NO)3 + Na3Po4 --> NaNo3 + PbPO4
Waxes - Carboxylic acids Waxes are the esters of higher fatty acids along with higher monohydric alcohols. The acids and alcohols generally found in waxes are palmitic, cerotic
Calculate the solubility product of AgCl. Ag 5- and Ag 10- nanoclusters having of metallic silver but nevertheless have standard potentials dissimilar from the potential of
HOW UNIT CELL AND SPACE LATTICE ARE RELATED TO EACH OTHER?
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A covered glass tube contains 2.25g of copper and 3.32g of sulphur. The mass of the tube as well as its contents is 18.48 g. Upon heating a chemical reaction forms copper(II) sulph
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The electron pair which forms a bond between two similar non-metallic atoms will be: (1) Dissimilar shared between the two (2) By complete transfer from one atom to other
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Hello. Do you know the rubric of what I need to know about chemistry because I am taking Chemistry this fall and I would like to know the basics
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