Complexation behaviour of the f-block, Chemistry

Assignment Help:

Q. Complexation Behaviour of the f-block?

Ions of actinide and lanthanide elements have a strong tendency to form complexes with a variety of oxygen and nitrogen donor ligands. Perhaps, because of their comparatively higher charge to size ratio, the actinide ions have a greater tendency to form complexes than the lanthanides. Also, because of the existence of a large number of oxidation states, the complexation behaviour of actinides is more varied. The lanthanide and actinide ions form the most stable complexes with chelating ligands such as oxalic acid, tartaric acid, citric acid, nitric acid, ethylenediamine tetraacetic acid (EDTA) and 0-diketones. In these complexes the metal ions have very high coordination numbers. For case, the coordination number of the metal ion in [Th(acac)4]. [Ce(N03)4.(OPPh3)2] and  [Ce(N03)6]2- is 8, 10, 12, respectively. In these complexes, the acetyl acetonate (acac) and the nitrate ligands are operating as bidentate ligands occupying two coordination sites around the metal ion. These metal ions form water soluble complexes with citric acid, tartaric acid and EDTA. The formation of water soluble complexes with these ligands facilitates separation of the metal ions by ion exchange chromatography.


Related Discussions:- Complexation behaviour of the f-block

The band model, The band model of solids is an extended of the molecular or...

The band model of solids is an extended of the molecular orbital (MO) method. The overlap of atomic orbitals in an extended solid produces rise to continuous bands of electronic en

What is mass of barium nitrate was used in the reaction, When a result of b...

When a result of barium nitrate and a solution of copper(II) sulphate are mixed a chemical reaction produces solid barium sulphate which sinks to the bottom and a solution of coppe

Electrocehmistry, . Explain the construction and working of Calomel electr...

. Explain the construction and working of Calomel electrode

Separation of inert gases, Describe the process involved inthe Dewar method...

Describe the process involved inthe Dewar method of separation of inert gases?

The velocity of hydrogen molecule, If the velocity of hydrogen molecule is ...

If the velocity of hydrogen molecule is 5x 10 4 cm sec -1   then its de-Broglie wavelength is: (1) 2 Å    (2) 4 Å    (3) 8 Å    (4)100 Å Ans:  4 Å

Isolation of compounds from plants, Can I get a compound from crude extract...

Can I get a compound from crude extract of plant by NMR and GC-MS?

Explain salt bridge with its functions., Salt bridge is a U-shaped tube con...

Salt bridge is a U-shaped tube containing a semi-solid paste of some inert electrolyte like  KCl, KNO 3 , NH 4 Cl,  etc. in agar-agar and gelatin. An inert electrolyte is one which

Find the number of degrees of freedom - single phase system, Find the numbe...

Find the number of degrees of freedom? Consider a single-phase system that is a gaseous mixture of N 2 , H 2 , and NH 3 . For each of the following cases, find the number of de

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd