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Q. Complexation Behaviour of the f-block?
Ions of actinide and lanthanide elements have a strong tendency to form complexes with a variety of oxygen and nitrogen donor ligands. Perhaps, because of their comparatively higher charge to size ratio, the actinide ions have a greater tendency to form complexes than the lanthanides. Also, because of the existence of a large number of oxidation states, the complexation behaviour of actinides is more varied. The lanthanide and actinide ions form the most stable complexes with chelating ligands such as oxalic acid, tartaric acid, citric acid, nitric acid, ethylenediamine tetraacetic acid (EDTA) and 0-diketones. In these complexes the metal ions have very high coordination numbers. For case, the coordination number of the metal ion in [Th(acac)4]. [Ce(N03)4.(OPPh3)2] and [Ce(N03)6]2- is 8, 10, 12, respectively. In these complexes, the acetyl acetonate (acac) and the nitrate ligands are operating as bidentate ligands occupying two coordination sites around the metal ion. These metal ions form water soluble complexes with citric acid, tartaric acid and EDTA. The formation of water soluble complexes with these ligands facilitates separation of the metal ions by ion exchange chromatography.
Interval Scales An alternative approach is to rate liking on a proper interval scale or on a continuous line - scale, with only the ends of the scale being labeled " extreme
The outer electronic structure 3s 2 3p 5 is possessed by: (1) Cl (2) O (3) Ar (4) Br ans: Cl
principle of qualitative analysis of funcional group
what are the conditions for heat to transfer?
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Ask A mixture of water and graphite is heated to 890 K in a 10 L container. When the system comes to equilibrium it contains 0.875 mol each of CO and H2 and 0.289 mol of H2O and s
Characteristics?
Q. In 1982, the International Union of Pure and Applied Chemistry recommended that the value of the standard pressure p o be changed from 1 atm to 1 bar. This change affects the
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