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A contact sulphuric acid plant burns pure sulphur with air. The products of combustion pass to a converter where some of the SO2 is converted to SO3 at a fast rate owing to the high temperature of the gas. However, because of an unfavourable equilibrium in high temperatures, the gas is cooled and sent to a final converter where the oxidation can be carried out further. The lower temperatures favours a greater conversion of SO2 and SO3. The gas from the first converter was found to contain 4.5 vol% SO2. The gas from the final converter contained 0.1% SO2 and 8% O2.
(a) What percentage of the total SO2 was converted to SO3 in the first and second converter?
(b) What was the excess air used to burn the sulphur?
Different types of breakdown: (i) Intrinsic breakdown ] (ii) Thermal breakdown (iii)Defect breakdown
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