Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Most ligands have a nonbonding electron pair that may react as a donor to empty orbitals on the metal atom. In ligands known as π acids or π acceptors a donor-acceptor communication also happens in the reverse direction. If a ligand has empty orbitals of π type symmetry with respect to the bond axis these may react as acceptors for electrons in filled metal orbitals of the correct symmetry. That is known as back donation. The commonest and simplest π acid ligand is carbon monoxide CO. This reacts as a donor in the normal way, through the acquired lone-pair orbital centered on carbon (the 3σ MO). The π antibonding orbital may also interact with filled d orbitals to produce the π-acceptor interaction. The combination of π-acceptor and σ-donor interaction is sometimes defined as synergic, as the electron wants in opposite directions facilitate each other.
Evidence for the π-acceptor communication comes from various sources.
Fig. 1. Bonding in CO complexes showing (a) σ overlap of CO lone-pair with empty metal d orbital, and (b) overlap of CO π* with occupied metal d
orbital.
what is inductomeric effect
the reaction equations for the dissociation of dithzone into chelate anions and the formation of metal-dithizone chelates
synthesis of di and tri substituted benzenes(symmetrical tribromo benzene, 2-amino-5methylphenol, 3-nitro-4-bromobenzoic acid, 3,4-dibromonitrobenzene, 1,2,3-trimethyl benzene) sta
concentration cell with out transference +salt bridge
how will you prepare iodoform in labarotary?
If n= 3 , then the value of which is incorrect: (1) 0 (2) 1 (3) 2 (4)3 Ans: 3
On mixing acetone and chloroform, a reduction in total volume occurs. What kind of deviations from ideal behavior for solutions is given in this case and why?
Elevation in boiling point : Mol. Mass = (1000 K b * w) /W+ ΔT In which, K b stands for Molal elevation constant of the solvent, w stands for Mass of the compoun
parts of ac generator
Explain the un-ionized form of vanillin It is the un-ionized form of vanillin that has the typical odor. In NaOH solution, the phenol group ofvanillin ionizes to its conjugate
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd