acceptor ligands -p (pi), Chemistry

Assignment Help:

 

Most ligands have a nonbonding electron pair that may react as a donor to empty orbitals on the metal atom. In ligands known as π acids or π acceptors a donor-acceptor communication also happens in the reverse direction. If a ligand has empty orbitals of π type symmetry with respect to the bond axis these may react as acceptors for electrons in filled metal orbitals of the correct symmetry. That is known as back donation. The commonest and simplest π acid ligand is carbon monoxide CO. This reacts as a donor in the normal way, through the acquired lone-pair orbital centered on carbon (the 3σ MO). The π antibonding orbital may also interact with filled d orbitals to produce the π-acceptor interaction. The combination of π-acceptor and σ-donor interaction is sometimes defined as synergic, as the electron wants in opposite directions facilitate each other.

Evidence for the π-acceptor communication comes from various sources.

 

2091_Untitled.png

 

Fig. 1. Bonding in CO complexes showing (a) σ overlap of CO lone-pair with empty metal d orbital, and (b) overlap of CO π* with occupied metal d

orbital.

 


Related Discussions:- acceptor ligands -p (pi)

Redox reactions, How do i balance the following equation: Ni+CO==>NI(CO)4? ...

How do i balance the following equation: Ni+CO==>NI(CO)4? I can''t figure out the oxidation state of Ni and C on the product side.

Dihydric alcohols - hydrocarbon, Dihydric alcohols - Hydrocarbon These ...

Dihydric alcohols - Hydrocarbon These are compound consisting of two hydroxyl sets. These are dihydroxy components of alkanes. Their common formula is A n H 2n+2 O 2 . The very

Peptide bonds, how is a peptide bond made through dehydration, showing a co...

how is a peptide bond made through dehydration, showing a complete chemical equation

Illustrate important catalyst of aluminium, Q. Illustrate important catalys...

Q. Illustrate important catalyst of aluminium? Anhydrous AlCl 3 is an important catalyst, used in organic synthesis and in the cracking of petroleum. Al 2 (S0 4 ) 3 as such o

What is standard enthalpy of formation, Q. What is Standard Enthalpy of For...

Q. What is Standard Enthalpy of Formation? Ans. It is really difficult to measure the total energy content or absolute entropy of a substance. In order to quantify entropy

Equivalent mass by hydrogen displacemnt, 0.205g of a metal on treatment wit...

0.205g of a metal on treatment with dilute acid gave 106.6ml of hydrogen collected over water at 755mm pressure and 17 degree Celsius. calculate the equivalent mass of the metal. (

Atoms, the periodic table

the periodic table

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd