Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Most ligands have a nonbonding electron pair that may react as a donor to empty orbitals on the metal atom. In ligands known as π acids or π acceptors a donor-acceptor communication also happens in the reverse direction. If a ligand has empty orbitals of π type symmetry with respect to the bond axis these may react as acceptors for electrons in filled metal orbitals of the correct symmetry. That is known as back donation. The commonest and simplest π acid ligand is carbon monoxide CO. This reacts as a donor in the normal way, through the acquired lone-pair orbital centered on carbon (the 3σ MO). The π antibonding orbital may also interact with filled d orbitals to produce the π-acceptor interaction. The combination of π-acceptor and σ-donor interaction is sometimes defined as synergic, as the electron wants in opposite directions facilitate each other.
Evidence for the π-acceptor communication comes from various sources.
Fig. 1. Bonding in CO complexes showing (a) σ overlap of CO lone-pair with empty metal d orbital, and (b) overlap of CO π* with occupied metal d
orbital.
a hittorf cell fitted with Ag-AgClis filled with HCl solution that contains 0.0003856g HCl/g water. A current of 2 mA is passed for exactly 3 hours. the solutions are withdrawn, we
The ratio of the energy of a photon of 2000Å wavelength radiation to that of 4000 Å radiation is: (1) 1/4 (2) 4 (3) 1/2 (4) 2 Ans
cxvzcx
Explain the un-ionized form of vanillin It is the un-ionized form of vanillin that has the typical odor. In NaOH solution, the phenol group ofvanillin ionizes to its conjugate
WhT is pollymara
what topic come under it to explain
how to find equivalent weight of a molicule
Why is that Li is the only element in group 1A that reacts with dinitrogen to a nitride
what is this
Criteria for determining the purity of organic compounds
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd