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"Nicotine in cigar smoke (pH 8.5) is much more readily absorped through the mucous membranes of the mouth than is nicotine in cigarette smoke (pH 5.3)..." [pKa for the pyridine NH (6-membered ring) is about 3, pyrrolidine NH pKa is about 8].
A. Use the Henderson-Hasselbalch and the definition of conjugate base/acid to determine the charge on most of the nicotine molecules or ions in the following pH ranges.
i. pH less than 3
ii. pH of 3 to 8
iii. pH of greater than 8
B. Use your answers in a. to explain the statement.
The resulting W3 was transferred to 500.0 mL of 1.00 M HCl. A 100.00 mL aliquot of the HCl solution required 10.13 mL of 0.08840 M potassium permanganate (KMnO4) to reach the purple endpoint. A blank required 0.18 mL. Determine the percent WO3 in ..
15 g of steam at 373 K is added to 250 g of H2O (liquid) at 298K at onstant pressure of 1 bar. Is the final state of the system steam or liquid water? Calculate changes in entropy for the process.
The crystal structure of lithium sulfide Li2S is pictured here. The edge length of the unit cell is 5.88*10^2pm. What is the density of Li2S in grams per cubic centimeter?
For each of the following unbalanced equations, indicate how many moles of the second reactant would be required to react exactly with 0.275 mol of the first reactant. Show all work below.
Nitric acid is usually purchased in a concentrated form that is 70.3% HNO3 by mass and has a density of 1.41 g/mL
Does ammonium chloride added to water produce a simple solution, does the ammounium chloride dissociate or does a chemical reaction occur resulting in a new set of compounds.
The protons that give rise to the signal at 7 ppm are more shielded than the protons that give rise to the signal at 9 ppm. B) The protons that give rise to the signal at 7 ppm are less shielded than the protons that give rise to the signal at 9 p..
How many carbon dioxide in kilograms is produced upon the complete combustion of 18.9 L of propane(Many home barbecues are fueled with propane gas
A canister is filled with 320 g of ice and 100 gm of liquid water, both at 0 C . The canister is placed in an oven until all the H_2O has boiled off and the canister is empty.
Electrochemical cell potentials can be used to determine equilibrium constants that would be otherwise difficult to determine because concetnrations are small
How much aspirin can be made from 100.0 g of salicylic acid and 100 g of acetic anhydride? If 122 g of aspirin were obtained by the reaction, what is the percent yield?
according to the following pKa values listed for a set of acids, which would lead to the strongest conjugate base?
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