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1. 1,3-diester is less acidic than a 1,3-ketoester, which is less acidic than an 1,3-diketone due to increased electron donation by the -OR group of the ester.
2. Claisen reactions use a stoichiometric amount of base and do not polymerize, unlike aldol reactions that use a catalytic amount of base and can polymerize.
3. Beta-hydroxy ketones can be formed by thiazolium catalysis with aldehydes.
4. Aliphatic heterocycles typically act like normal ethers, amines, and thioethers unless there is a large amount of ring strain.
What minimum votage is required to electrolyze anhydrous HF. the H-F bond is so polar that liquid HF is essentially composed of H^+ and F^- ions.
The reactant concentration in a zero-order reaction was 9.00×10-2M after 175 s and 4.00×10-2M after 325 s. What is the rate constant for this reaction?
A biochemical engineer isolates a bacterial gene fragment and dissolves a 10mg sample in enough water to make 30ml of solution. the osmotic pressure of the solution is .340 torr at 25 degrees C. the molar mass of the gene fragment is 1.81x10^4 g/m..
The catalytic converter on your automobile contains small amounts of a precious metal catalyst. Which of the following components would you expect to be decreased in your tailpipe emissions.
Calculate the weight of potassium chlorate required to prepare 380 mL of wet oxygen collected over water at 20 Celcius and 750 mm of Hg.
A mixture of gases contains 2.42 g of Kr, 4.58 g of Ar, and 5.74 g of NO2. What is the partial pressure in atm of each component of this mixture if it is held in a 11.5-L vessel at 31.3 oC? Use R = 0.0821 L-atm/mol-K as the value of the gas consta..
A 4.90 g nugget of pure gold absorbed 266 J of heat. What was the final temperature of the gold if the initial temperature was 23.0°C? The specific heat of gold is 0.129 J/(g·°C).
What is the molecular formula of a product obtained by adding fluorine to 1-butene and then cracking out
What is the overall charge state for the tetrapeptide DREAM at physiological pH. The pK values for N-terminal, C-terminal, side chain of asp, arg, glu
A 150.0 ml flask contains 0.391 grams of volatile oxide of sulfur. The pressure in the flask is 750mmHg and the temperature is 22 degrees Celsius.
A backpacker wants to carry enough fuel to heat 2.9 kg of water from 27 degrees C to 100.0 degrees C. If the fuel he carries produces 36 kJ of heat per gram when it burns, how much fuel should he carry? (For the sake of simplicity, assume that the..
What is the boiling point of a solution made by adding 6.79 g of magnesium chloride to 242.0 g of water?
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