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You are investigating the metabolism of the amino acid aspartate in E. coli. After a transamination it enters the TCA cycle as oxaloacetate. If you radiolabel all the carbon atoms of aspartate equally, what fraction of the radioactivity will appear as CO2 during the first 2 turns of the TCA cycle? Draw the structure of OAA and indicate its labeling pattern after the second turn of the TCA cycle.
Given a 4.50 L container of helium at 298 K and 1.00 atm, and a 3.00 L container of argon at 298 K and 1.00 atm, write a brief statement to explain whether or not atoms of He and Ar in their respective containers have the same average speed.
A 14.0-g sample of CaCl2 is dissolved in 112 g of water, with both substances at 25.0°C. Calculate the final temperature of the solution assuming no heat lost to the surroundings and assuming the solution has a specific heat capacity of 4.18 J/°C ..
Looking at the nickel complexes as an example, it is found that those formed with ammonia give the complex [Ni(NH3)6]^2+ and when formed with ethylenediamine the complex [Ni(en)3)^2+ is the result.
"A mixture of CH4 and H2O is passed over a nickel catalyst at 100 degrees K. The emerging gas is collected in a 5.00-L flask is found to contain 8.62g of CO, 2.60 g of h2, 43.0 g of CH4, and 48.4 g of H2O.
What is the product of toluene+ conj base of alcohol? ( a ring with a O- ) also, where does equilibrium lies?
How does one predict the regiochemistry of the products of aromatic reactions like nitration? What factors are responsible for the product ratios seen in such reactions?
Enough of a monoprotic acid is dissolved in water to produce a 0.0194 M solution. The pH of the resulting solution is 6.26. Calculate the Ka for the acid.
Methanol is toxic for humans if they ingest liquid methanol or inhale methanol vapor in significant quantities. When inhaled in concentration greater than 1000 ppm, death has been reported.
The reaction of 2.5g of Al with 2.5g oxygen (actually) produces 3.5g of Al oxide. Calculate the % yield of aluminium oxide.
You have two gas tanks, one is 7.00 L and the other is 3.50L, and one of the tanks has oxygen in it and the other has acetylene. If the tank wth the oxygen has a pressure of 145 atm, what is the pressure of the other tank?
Given that Ea for a certain biological reaction is 48kJ/mol and that the rate constant is 2.5 x 10^-2 s-1 at 15 degrees celsius
A cylindrical steel pipe is used to transport hydrogen gas in a certain process. The density of the hydrogen in the pipe is 5kg/m3 and the density in the environment is effectively zero
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