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For a certain glass electrode, the selectivity coefficient for Na+ relative to H+ is 1.0 x 10-12. The electrode is calibrated with NBS standard buffers 6.86 and 9.18, which produce no significant response to interfering ions. It is then used to measure the pH of 0.0100 M NaOH in 0.50 M NaCl at 25 oC.
What is the true pH of the solution and the observed pH? Use the Debye-Huckel equation to estimate acitivity coefficients.
How many mL of each solution should be diluted to 500 mL to make 0.100 M reagent?
light of wavelength 221nm striking a sample of tungsten causes electrons to be ejected with a speed of 6.04x10^5 m/s. calculate the work function of tungsten
The concentration of phosphoric acid in Coke is approximately 106.0 mg/mL. Assuming phosphoric acid is the only acid in Coke, calculate the pH of a 355 mL can of Coke.
an empty flask has a mass of 123.4 grams. when the flask is filled with water, the mass is 211.6 grams. if 10 grams of zinc (density=7.14g/cm3) are added to the flask filled with water, what is the new mass of the flask?
At 20 degrees C the vapor pressure of pure methanol (CH3OH) is 89.0 torr and of pure water (H2O) is 17.5 torr. A solution of methanol and water has a total vapor pressure of 52.9 torr at 20 degrees C.
Draw graphs representing Boyle's law, Charles's law, and Gay-Lussac's law for a fixed amount of gas. Make sure that you label each axis and state the assumptions for each law-that is, the variable(s) that is (are) held constant for each law.
The Solubility of Mg(OH)2 (s) in wataer at a certain temperature is 1.0 x 10^-4 mol/L. Calculate the value of Ksp for Mg(OH)2 (s) at this temperature.
how many moles of oxygen are required to react completely with 5 mol C8H18?
Determine the molar mass of aspartame and How many moles of molecules are in 10.0g of aspartame?
How many mL Hydrochloric acid of 0.1 M must be added to 100 mL of a 0.2 M solution of tris base to form a buffer ( pH 7.8)?
A soluation of HO-CH2-CH2-OH is prepared by dissolving 651g of ethylene gylcol in 1.50kg of water. Determine the freezing point of the soluaiton and the vapor pressure of water above the solution 25.0 degrees C.
Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+. [Ksp (PbI2) = 1.4 × 10-8; Ksp (AgI) = 8.3 × 10-17] Calculate the Ag+ concentration when PbI2 just begins to precipitate.
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