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By using photons of specific wavelengths, chemists can dissociate gaseous H-I to produce H atoms with accurately known speeds. When H-I dissociates, the H atoms move away rapidly, whereas the relatively heavy I atoms move little. Average Bond Energies
(a) What is the longest wavelength (in nm) that can dissociate a molecule of H-I?
(b) If a photon of 253 nm is used, what is the excess energy (in J) over that needed for the dissociation?
(c) If all of this excess energy is carried away by the H atom as kinetic energy, what is its speed (in m/s)?
What is the electron-pushing mechanism for the aldol condensation reaction of benzaldehyde and acetone forming dibenzalacetone
A galvanic cell is produced as follows: Left half-cell has a Pt wire dipping into a beaker containing an equimolar mixture of Cr+2 and Cr+3 . [Cr3+ + e-??Cr+2 E°-= -0.42 V] Right hand cell has a Tl rod immersed in 1.00 M TlClO4. [Tl+1 + e-??Tl(s) ..
What is the theoretical yield for this reaction under the given conditions:1.49 g H2 is allowed to react with 10.3 g N2
The models you have just studied represent achiral molecules. Their mirror images are identical. They are optically inactive. Any molecule that has a plane of symmetry is achiral.
The isothermal compressibility of graphite is 1.56 × 10-7 bar-1. At what pressure is density equal to density of diamond?
Is this system at equilibrium? If not, will the amount of N(g) increase or decrease as the system proceeds to equilibrium at 4000 k in a fixed volume
At what pH will this occur? Ignore complex formation and potential redox reactions.
The vapor pressure of water at 32 C is 35.7mmHg. What is the vapor pressure of water-ethylene glycol solution at 32 C? Ethylene glycol is non-volatile.
60.0 mL of a 0.450 M solution is titrated with 0.570 M . Calculate the volume of required to reach the equivalence point.
Identify the element oxidized and reduced in the following redox rxn. Also indicated the number of electrons lost/gained by each atom.
Heat is lost to the styrofoam calorimeter. Assuming a 6.22 C temperature change for the reaction of HCl(aq) with NaOH(aq), calculate the heat loss to the inner 2.35-g styrofoam cup. The specific heat of styrofoam is 1.34 J/gC.
Consider the four equations of states(EOS) below describing PVT behavior of gases. Let a and b be constants. EOSI : PV = RT EOSII: (P-a)V = RT EOSIII: P(V-b) = RT EOSIV: P = RT/(V-b) - a/V (a) Prove for EOSI that both U and H are functions of T on..
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