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In the acrogenic process introduced in Problem 15.1, the catalyst is packed in tubes and the reactor is cooled using a circulating molten salt. The molten salt rejects heat to boiling steam in a similar arrangement to that shown for phallic anhydride in Figure 15.25. The required gas hourly space velocity is 200 standard liters (at STP)/liter.h. Design and size a reactor to produce 20 kt/y of acrogenic.
Problem 15.1
Acrolein (H2C=CHCHO) is made by selective oxidation of propylene at 2 bar, 350 °C using a molybdenum, iron, and bismuth catalyst on a silica support. The reactor yields based on propylene are 85% acrolein, 10% acrylic acid, and 5% light by-products. The light byproducts are mostly acetaldehyde, but for the purpose of this problem it can be assumed that the yield is 85% acrolein and 15% acrylic acid. The feed to the reactor on a volume percent basis is propylene 6%, propane 28%, steam 6%, oxygen 11%, and balance nitrogen. Estimate the reactor cooling requirement for a plant that produces 20,000 metric tons per year (20 kt/y) of acrolein if the reactor is operated isothermally.
Calculate the light fluence rate integrated over a sphere of a 5-cm radius centered at the source.
Consider the solenoid with a core of square cross section shown in Figure P12.4.6.
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Assume negligible miscibility between the aqueous and organic liquids in each other, and ignore any change in density on removal or addition of the enzyme to either stream.
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In the reaction 2C8H18 + 25O2 --> 16CO2 + 18 H2O, the ratio of volumes of O2 to CO2
Assume you. have a photodctcctor with a current rcsponsi vity of 5 AJW. A continuous wave HeNe laser with wavelength of 632.8 nm and spot size of 0.5 mm2 is incident on the active area of the detector. Assume that 6.37 x 1021 photons per m..
A string of negligible diameter is drawn down the center-line of a pipe containing a Newtonian fluid. At what velocity, w, must the string be drawn in order to vaporize the fluid?
Wal-Mart is the largest corporation in the world, and it has obviously enjoyed tremendous success. But while many welcome its location in their communities, others do not. Some complain that its presence has too many negative effects on a communit..
Compare MACRS depreciation and straight-line depreciation: based solely on the tax effects, which depreciation method (SL or MACRS) would yield a higher net present value for the project?
If the mass percent of vanadium in the ore was 58.1%, what was the mass of the ore sample? Which of the four transition metal ions in this titration has the highest oxidation state?
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