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Question 1
With regard to the asymmetric Heck reaction - from the rccent literature (2010-2014) please give three examples that use the intermolecular and three examples that employ the intramolecular asymmetric Heck reactions as key steps in total synthesis or as steps studied for asymmetric methodology development.
In your analysis of these publications outline the chiral ligands used and draw a catalytic cycle for one initermolecular and one intramolecular reaction.
Question 2:
With regard to the asymmetric palladium - catalysed allylic substitution reaction - from the recent literature (2010-2014) please give five examples that use this transformation as ahoy step in total synthesis. In your analysis of these publications outline the chiral ligands used and draw a catalytic cycle for one of the examples you have chosen.
(a) Describe the provisions of Occupational Safety and Health Act 2005 with regard to ‘Substances hazardous to health' (b) Describe four types of hazard which arise from the use of chemicals
Prepare the design and evaluation of a new chemical manufacturing process.
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What is the drawdown at the perimeter of the well pumping 225 gpm when both wells are operating?
Calculate the molar fraction of the system in the vapor phase
What does LD 50 mean in Industrial Toxicology and What is its significance to workers handling pesticides What units are used to quantify the standard service illuminance for specific work activities? Name the instrument used to appraise the lig..
Determine the d-spacing (Å), to 3 decimal places
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The potential energy between two atoms A and B are constants and r the interatomic separation distance.
Discuss how transmission electron microscopy (TEM) can provide information complementary to that which can be obtained from standard X-ray or neutron diffraction methods, giving suitable examples.
ECH 3023: Mass Balance around two distillation Columns Using Excel, Derive the simultaneous linear mass balance equations for the system using all the information provided.
It is common that people are exposed to more than one hazardous substance at a time. The different substances may interact such that one substance may alter the toxicity of one or more of the chemicals present. Discuss the possible interactions th..
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