Define derived rate law agree with the experimental rate law

Assignment Help Chemistry
Reference no: EM13526357

the mechanism for the reaction 2No +O2----> 2NO2. is believed to involve the following steps: 1- 2NO<----> N2O2 fast (k1,K^-1)
2- N2O2 +O2---> 2NO2 slow

1- derive the rate equation using the steady state approximation for any intermediates.

2- experimentally the rate law is determined to be third order. under what conditions (if any) does your derived rate law agree with the experimental rate law?

3- describe two experiments and the results that would allow you to test the mechanism.

Reference no: EM13526357

Questions Cloud

What is the kangaroos horizontal speed : A gray kangaroo can bound across a flat stretch of ground with each jump carrying it 9.0m from the takeoff point. What is the Kangaroos horizontal speed
Explain the highest ph value : Which of the following solutions would have the highest pH value. Assume that they are all initially 0.10 M concentrations of weak acid at 25 degree C.
Find the magnitude of the normal force that the ground exert : A woman at an airport is towing her 23.5-kg suitcase at constant speed by pulling on a strap at an angle ? above the horizontal. What is the magnitude of the normal force that the ground exerts on the suitcase
Determine ending inventory under perpetual inventory system : Determine the ending inventory under a perpetual inventory system using (1) FIFO, (2) moving-average cost, and (3) LIFO and which costing method produces the highest ending inventory valuation?
Define derived rate law agree with the experimental rate law : Experimentally the rate law is determined to be third order. under what conditions (if any) does your derived rate law agree with the experimental rate law
Find the angle between the string and the horizontal : The string of a conical pendulum is 54.0 cm long and the mass of the bob is 0.27 kg. Find the angle between the string and the horizontal when the tension in the string is eight times the weight of the bob
Evaluate the activation energy and exponential factor : A reaction has a rate constant of 0.00117 s^-1 at 400 k and 0.689s^-1 at 450 k.1- Calculate the activation energy (Ea) and the pre- exponential factor (A) for this reaction. 2- what is the value of the rate constant at 425k
Compute the overall effect of these transactions : Compute the overall effect of these transactions on the company's reported income for 2009. Is reported net income overstated or understated?
How much of the machine setup cost pool : One of Lara Dole Company's activity cost pools is machine setups, with estimated overhead of $300,000. Dole produces flares (400 setups) and health packs (600 setups). How much of the machine setup cost pool should be assigned to flares?

Reviews

Write a Review

Chemistry Questions & Answers

  If the temperaure changes from 220oc to 275oc and the

you heat a 454 gram aluminum pot to cook some mac amp cheese. if the temperaure changes from 22.0oc to 275oc and the

  Explain vapors are likely to be non-ideal near condensation

Vapors are likely to be non-ideal near condensation temperatures. Would you expect such behavior to make your molecular mass to high or too low?

  State grams of water with excess sulfur dioxide

According to the following reaction, how many grams of sulfurous acid (H2SO3) will be formed upon the complete reaction of 21.5 grams of water with excess sulfur dioxide? sulfur dioxide (g) + water (l) sulfurous acid (H2SO3) (g)

  Explain covalent bond in methyl salicylate and water

What covalent bond in methyl salicylate and water were broken during reaction of converting methyl salicylate to salicylic acid?

  How to compute the ionization energy of a hydrogen atom

Ionization energy is the energy needed to eject an electron from an atom. Compute the ionization energy of a hydrogen atom in its first excited state (n = 2).

  Determine the amount of heat required

Determine the amount of heat required to raise the temperature of a 153 g bar of gold by 50.0C. (specific heat of gold = 0.128 J/g.C)

  Explain co2 are produced by an incandescent lightbulb

About how many gallons of CO2 are produced by an incandescent 60-W lightbulb burning for an hour

  Solid silicon and solid magnesium chloride form when

solid silicon and solid magnesium chloride form when silicon tetrachloride gas reacts with magnesium metal. write a

  Find out the strategies from discussion group which you

considernbspthe following scenario in your assigned discussion group phoenix homeless agency pha needs funds to

  Explain what is the empirical formula for the oxide of iron

magnetite was found to contain 2.5698 g of iron and 0.9816 g oxygen. What is the empirical formula for this oxide of iron?

  State the mechanism to convert nine-fluorenol

the mechanism to convert 9-fluorenol to 9-methoxy fluorene using a nucleophilic substitution reaction with H2SO4 and methanol.

  Explain what is poh of the resulting solution

Consider the addition of 22.59 mL of 0.1643 M aqueous HCl to 19.01 mL of 0.1558 M aqueous NaOH at 25°C. Assuming the volumes are additive, what is pOH of the resulting solution?

Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd