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Standard addition. An unknown sample of dopamine gave a current of 34.6 nA in an electrochemical analysis. Then 2.00 mL of solution containing 0.0156 M dopamine was mixed with 90.0 mL of unknown, and the mixture diluted to 100.0 mL in a volumetric flask. The signal from the new solution was 58.4 nM. What was the dopamine concentration in the unknown?
NO+ and NO- are also known. Compare the bond orders of these ions with the bond order of NO. Which of the three would you predict to have the shortest bond? Why?
At 25 degrees Celsius, .87 atm of No2(g) was allowed to decompose. At equilibrium it was found that the partial pressure of no2(g) was .81 atm. Calculate the value of kc at the temperature
Problem- Assume that blood is mostly water. The Henry's law constant for N2 in water at 300 K is 86,000 atm. The hydrostatic pressure acting on a diver is 1 atm at the surface, and increases by approximately 1 atm for every 33 ft of depth.
Hard water often contains dissolved Ca2+ and Mg2+ ions. One way to soften water is to add phosphates. The phosphate ion forms insoluble precipitates with calcium and magnesium ions
Problem- If 25 mL of 0.10 M NaOH is added to 35 mL of 0.20 M HC2H3O2, what is the pH of the resulting solution at 25°C? Ka for HC2H3O2 is 1.8 x 10-5 at 25°C.
Explain how many constitutionally isomeric monochlorides can be formed on free radical chlorination of 2,3,4-trimethylpentane
A 4.22g sample of CuS was added to excess HCl, and the resulting H2S was collected over water. What volume of H2S was collected at 32 degrees celsius
What volume of 2.0 M NaClO must be diluted with water to prepare 500.0 mL of 0.10 M NaClO?
A sample of air contains 78.08 % N2, 20.94% O2, 0.05 %CO2, 0.93% Ar by volume. a) How many molecules of each gas present in 1.00 L sample at 25 C and 1.00 atm. b)What is the partial pressure of each gas?
The gas phase reaction A + B ® C has a reaction rate which is experimentally observed to follow the relationship rate = k[A]2[B]. Which one of the following would affect the value of the specific rate constant
What was the concentration, in mol/L and mg/L, of Cu^2+ and Zn^2+ in the original solution? If the solution was prepared by dissolution of 0.654 g of brass in 250.00 mL solution, what the percentage of copper and zinc in the original sample of bra..
for the equilibrium below at 400 k kc7.br2 g cl2 g -gtlt- 2brclgif initially .30 mol of br2 and .30 mol cl2 are
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