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1. Suppose a metal single crystal is loaded (stressed) in the [1 0 1] direction. a. If the critical resolved shear stress for this material is 0.34 MPa, what magnitude of applied stress is necessary for dislocations to begin to move in the (1 1 1)[-1 1 0] slip system? b. If the slip system listed in part a is valid, does this metal have the FCC, HCP, or BCC crystal structure? 2. Suppose you have an FCC metal single crystal which is known to have a critical resolved shear stress of 55.2 MPa. a. Find the largest normal stress that could be applied to a bar of this material in the [1 1 2] direction before dislocations begin to move in the [1 0 -1] direction on the (1 1 1) plane. b. How does your answer change if it is a BCC crystal and the slip system is [1 1 1](1 0 -1) (with the same shear stress)? 3. Consider the crystal structure for CaTiO3 (the perovskite structure) in which Ca2+ ions are located at the simple cubic positions, O2- ions are located at the six face centers, and the Ti4+ ion is at the 1/2, 1/2, 1/2 position. Determine the direction and length of the lowest-energy Burgers vector for this compound.
Calculate the pZn of a solution prepared by mixing 25.0 mL of 0.0100 M EDTA with 50.0 mL of 0.00500 M Zn2+. Assume that both the Zn2+ and EDTA solutions are buffered with 0.100 M NH3 and 0.176 M NH4Cl to provide a constant pH of 9.00.
Problem- For a process at constant temp what is the relationship between Gibbs free energy and the changes in enthalpy and entropy for the system
determine the end value of n in a hydrogen atom transition if the electron starts in n2 and the atom absorbs a photon
A 75 mL solution of 0.030 M Ca(OH)2 is titrated with 0.035 M HCl. Calculate the pH of the mixture after 60 mL of HCl have been added.
If you start with 1.000 g of sulfur (S8) and obtain 4.963 g of pure compound. What is the empirical formula of this compound?
the reaction below was allowed to proceed to equilibrium. thecontents of a 2 liter reaction vessel were then subjected
Suppose you dip a string in a supersaturated sugar solution to make rock candy. The string is dipped in corn syrup, then sugar, then placed in the sugar solution. After a few days of sitting in the solution, the string should have some rock candy ..
Calculate the number of liters occupied at STP: a. 1.7 mol H2(g); b. 1.8 x 10-2 mol N2(g); c. 2.5 x 10(2) mol O2(g)
Add the angular wave function for a 2s electron of Carbon to that of a 2py electron of the same carbon atom. Subtract one from the other. In what direction do the functions point? What orbitals are "left" unused on the C atom?
in hundreds of thousands of homes across the country family swimming pools and spas require sanitation and maintenance
Explain an aqueous of solution of phosphoric acid typically 5% by weight H3PO4, p=1.03 g mL-1 is sometimes used to remove deposits in a power plant.
In fact as the temporary sure not far above the boiling point of the liquid, the gas is not ideal. Explain how this would affect the results of the molecular weight determination.
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