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Theory of Meta directing group
The substituent, S takes electrons from para and ortho positions. So, m-position becomes a position of comparatively high electron density and further substitution through electrophile occurs at Meta position. For instance, -NO2 group is a Meta directing (Electron withdrawing). Its procedure can be demonstrated as:
All meta-directing sets comprise either a partial positive charge or a full positive charge on the atom straight attached to the ring.
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Energy of electron of hydrogen atom in second Bohr orbit is: (1)-5.44x10 -19 j (2)- 5.44x10 -19 kj (3)-5.44x10 -19 cal
examples and uses of separation technique
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