Illustrate Magnetic properties of f-block element, Chemistry

Assignment Help:

Q. Magnetic Properties of f-block element?

You have learnt in the preceding unit-that paramagnetism is related with the presence of unpaired electrons in a substance. The actinide and lanthanide ions,  other than type (e.g.  La3+, Ce4+, Ac3+, Th4+, Pa5+, U6+, and f14 type ( e, g Yb2+ Lu3+ Lr3+paramagnetic, due to each of the seven f orbitals charactering inner -transition metal  species (lanthanide and actinide) must have a single electron before any pairing can take  place (Hund's rule).

You have also studied that in case of transition elements; the contribution of orbital motion of electrons to paramagnetism is negligible and will be ignored. The magnetic moments of transition metal ions can be explained in terms of unpaired electrons present in d-orbitals.  But the magnetic moments of only those lanthanide ions, which have,f0 f7and f14 configuration agree with the spin only value. In all other cases, the magnetic moment value are higher than those evaluated on the basis of spin only formula. Though, these can be explained by taking orbital contribution to magnetic moment also into account. In lanthanide ions, the 4f orbitals are comparatively better shielded from the surroundings by the overlying 5p and 5s orbitals than the d orbitals in transition metal ions. Thus, the contribution of orbital motion to paramagnetism is not quenched. 

Although actinides show a variation in magnetic properties same to that of the lanthanides, the magnetic properties of the actinide ions are more complicated than those of the lanthanide ions. This in part arises from (i) the fact that the 5f electrons are nearer the surface of the atom and are easily influenced by the chemical environment; although not to the similar extent as do the d electrons, and (ii) the less sharply illustrate distinctions between 5f and 6d electrons as compared with 4f and 5d electrons. From the above discussion it is clear that the magnetic moments of the f-block (inner transition) metal ions have to be calculated taking into account both spin and orbital contributions.


Related Discussions:- Illustrate Magnetic properties of f-block element

Which geometry does have formaldehyde molecule, Which geometry does have Fo...

Which geometry does have Formaldehyde molecule The formaldehyde molecule has trigonal planar geometry. Therefore, both the H-C-H bond angle and the H-CAO bond angle are abou

Why we need sulfuring, Q. Why we need Sulfuring? Sulfuring is the proce...

Q. Why we need Sulfuring? Sulfuring is the process which is used to destroy microorganisms and to preserve colour. Fruits after blanching may be dipped into a sulphite solution

Explain about phosphprous and its allotropes, Explain about Phosphprous and...

Explain about Phosphprous and its allotrpes White phosphorus - crystalline solid P 4 Red phosphorus - polymeric solid Scarlet phosphorus Violet phosphorus

Discuss cohesive energy and electron affinity, Discuss "cohesive energy" an...

Discuss "cohesive energy" and "electron affinity". ‘Cohesive energy’:  In a chemical bond, it’s the energy required to dissociate a solid into isolated atoms or molecules as ap

What are primary cells and explain its reactions?, This type of cells becom...

This type of cells becomes dead over a period of time and the chemical reaction stops. They cannot be revitalized or used again. Some ordinary examples are dry cell, mercury cell,

Mole fraction, The mole fraction of solute and solvent is equal to

The mole fraction of solute and solvent is equal to

Oxidation of propene to propan-1-ol, Which of the following is ideal for Ox...

Which of the following is ideal for Oxidation of propene to propan-1-ol a)Alkaline KMnO 4 b)B 2 H 6 /Alkaline KMnO 4 c)O 3 /Zn dust d)CrO 3   Ans) B 2 H 6 /Alkaline KMno4 is th

Nylon (polyamides), Nylon (polyamides): S ynthetic fibre forming polyamides...

Nylon (polyamides): S ynthetic fibre forming polyamides are also termed as Nylons. Therefore, Nylon is well known in the textiles. Nylons are those polymers which contains a repeat

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd