Explain oriental polarisation, Chemistry

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Explain oriental polarisation.

Orientational Polarisation: When two different atoms form a chemical bond, one of the two is more probable to part with one or more of valence electrons of it than the other. While ZAe and ZBe shows the nuclear charges of the two atoms where Z shows the atomic numbers and if A atom has a tendency to provide valence electrons to the atom B, therefore there are more than ZB electrons around the nucleus of atom B and less than ZA electrons around atom A. Therefore atom A is more electropositive than atom B. Accordingly, the bond in between A and B may be said to be of an ionic type and therefore this is clear that the molecule AB carries an electric dipole moment even in the absence of an electric field. For molecule having more than two atoms, some bonds may carry a permanent dipole moment and the resulting permanent dipole moment as a complete is obtained through vector addition of the moments related with the various bonds. While an external field 'E' is applied to a molecule carrying a permanent dipole moment, the former will going to align the permanent dipole along the direction of E. The contribution of this process of orientation of permanent dipoles to the polarisation P is termed as Dipolaror or Orientational Polarisation.


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