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Linkage isomerism
Some ligands are ambidentate, mean that they can coordinate by alternative ligand atoms. Instances are nitrite NO2- (that can bind via N or O) and thiocyanate SCN- (S or N). The nomenclature N-nitrito and Onitrito is suggested for complexes in which, in the formulae the ligand atom is underlined, M-NO2 and M-ONO correspondingly (even though the nonsystematic names nitro and nitrito are also employed for NO2- complexes).
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