Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
According to this theory, the impure iron surface behaves like a small electrochemical cell presence of water containing dissolved oxygen or carbon dioxide. Such a cell is also called corrosion cell or corrosion couple. In these miniature corrosion cells, pure iron acts as anode and impure surfaces acts as cathode. Moisture dissolved oxygen or carbon dioxide in it comprises electrolytic solution.
At anode, oxidization of Fe atoms takes place. Thus, Fe atoms pass into solution as Fe2+ ions leaving behind electrons in the metal which are pushed into cathodic area. Fe Fe+2 + 2e-; = - 0.44 V (i)
At cathode, the electrons are picked up by the H+ ions which are produced either from H2O or from H2CO3 (formed by dissolution of CO2in moisture). CO2 + H2O H+ + HCO3- 2H+(aq) + 2e- 2H The H atoms, thus, formed, reduce the dissolved oxygen as 2H + ½ O2 H2O The net reduction process at the cathodic area is 2H + ½ O2 + 2e- H2O; = 1.23 V (ii)
The net reaction of the corrosion cell can be obtained by adding equations (i) and (ii) F2 + 2H+ ½O2 2 Fe2+ + H2O; = 1.67 V The ferrous ions so formed move through water and come at the surface of iron object where these are further oxidized to ferric state by atmospheric oxygen and constitute rust which is hydrated iron (III) oxide. 2Fe2+ + ½ O2 + 2H2O Fe2O3 + 4H+ Fe2+ + xH2O Fe2O3xH2O (rust)
structure of 2-ethylbutanoic acid
Calculate the energy required to compress carbon dioxide from 1 bar to 50 bar (final volume is 50 ml, 298 K, ideal gas).
The structure of spiropentadiene The structure of spiropentadiene is shown below; it undergoes a Diels-Alder reaction with two molar equivalents of 1,3-cyclopentadiene. Spirope
what is oxidation?
The correct electronic configuration of Ti(Z= 22) atom is: (1) 1s 2 , 2s 2 , 2p 6 , 3p 6 , 4s 2 , 3d 2 , (2) 1s 2, 2s 2 , 2p 6 , 3p 6 , , 3d 4 , (3) 1s 2 , 2s
a student prepared a solution of sodium carbonate by 2.111g of the solid to a 250.0ml volumentric flask and adding H2O to the mark.Some of this solution was transferred to a burett
General principles for naming organic compounds In the general system, all the isomeric alkanes (having similar molecular formula) have the the same parent name. The names of
Uses of methane - Alkanes (1) In the development of compounds such as formaldehyde, methyl chloride, methyl alcohol, chloroform, carbon tetrachloride, etc. (2) In the prepar
How to know degree of superheat from psychometric chart?
Q. Show the Liquation in purification of metals? Crude tin, bismuth and lead are purified by liquation. In this process, the impure metal is placed at the top of a sloping hear
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd