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The f-block elements contains of two series of inner transition elements i.e. lanthanoids (the fourteen elements subsequent lanthanum) and actinoids (the fourteen elements subsequent actinium). They are also called rate earth elements. All the lanthanoids have electronic configuration with 6s2 common but with variable occupancy of 4f- and 5d- subshells. All actinoids have electronic configuration of 7s2 and variable occupancy of 5f- and 6d- subshells. These f-orbitals are placed to the shell third from the outer shell. This factor accounts for some characteristic properties of these elements. The members of lanthanoid and actinoids series are listed in the table below. Although lanthanum itself does not possess any 4f-electrons, it is customary to include this element in the discussion of lanthanoid series due to its close resemblance with lanthanoids. For lanthanoids the general symbol, Ln is often used. Similarly, actinium is studied alongwith actinoids. The electronic configuration of the elements with fully filled (f14) and half filled (f7) f-orbitals are relatively more stable. The extra stability of half filled orbitals is seen in the elements europium (4f7 6s2) and gadolinium (4f7 5d1 6s2). The element ytterbium has fully-filed f-orbitals with the configuration 4f14 6s2 and the extra electron in lutetium goes in 5d-orbitals (4f14 5d1 6s2). So except for lanthanum, gadolinium and lutetium which have a single electron in 5d-orbitals the lanthanoids do not have electrons in the 5d-orbitals. Electronic configuration of Lanthanum and lanthanoids Electronic configuration of actinium and actinoids
Which of the following is ideal for Oxidation of propene to propan-1-ol a)Alkaline KMnO 4 b)B 2 H 6 /Alkaline KMnO 4 c)O 3 /Zn dust d)CrO 3 Ans) B 2 H 6 /Alkaline KMno4 is th
Q. Explain about Multidentate ligand? A multidentate ligand which combines with a metal ion through two or more atoms on the ligand simultaneously is called a cheldting agent.
The series limit for Balmer series of H-spectra is: (1) 3800 (2) 4200 (3) 3646 (4) 4000 Ans: 3646
How do we solve numerical problems in double titration
Name the chemical components which constitute nucleotides. Write any two functions of nucleotides in a cell.
Molecule in itself is electrically stable so it cant act as ligand So that it can acts as the negative and pasitive ligand.
assignment on antiferromagnatism
what is wet test for acid redicals?
Bakelite: It is thermosetting plastics which are most widely used and the most important plastics. Preparation: It is formed by condensation reaction of phenol an
The electronic configuration of calcium ion ( Ca2 + ) is: (1) 1s 1 , 2s 2, 2p 6 , 3s 2 , 3p 6 , 4s 2 (2) 1s 1 , 2s 2 , sp 6 , 3s 2 , 3p 6 , 4s 1
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