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Given the following thermodynamic information, develop the Ag-CN-H2O Eh-pH diagram for a solution containing 1 × 10-3 M [Ag] and 5 × 10-3 M [CN] at 25oC. Please show all work
SPECIES
ΔGo, kcal/mol
Ago
0.00
Ag+
18.44
AgO
3.50
Ag2O3
29.01
AgO2
-2.63
Ag2O
-2.68
Ag(CN)2-
73.04
HCN
26.77
CN-
39.67
H2O
-56.69
with surface charge density sigma
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