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The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process.
a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.
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Calculate the force constant of CF4 and SiF4 and compare their relative strengths with each other. The heats of formation of CF 4 and SiF 4 are -1222 kJmol -1 and -1615
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What are the limitations of valence bond theory?
Q. Show the Structure of sulphuric acid? Theoretical considerations require that the reaction be carried out at low temperature and high pressure. However, at low temperature,
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