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Nitrenes - Organic Chemistry
(1) The nitrogen analogous of carbenes are termed as nitrenes.
(2) There is probability of two spin structure for nitrenes depending upon whether the two non-bonding electrons (the normal nitrogen lone pair remains paired) comprise their spins paired or parallel.(3) generally nitrenes obey Hunds rule and the ground state triplet along with two degenerate sp-orbitals containing a single electron each.
The equilibrium cell potential of the galvanic cell Pt | H 2 (g, f =1 bar) HCl (aq, 0.500mol kg -1 ) | Cl 2 (g, f =1 bar) | Pt is found to be E cell, eq = 1.410V at 298.15
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