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Nitrenes - Organic Chemistry
(1) The nitrogen analogous of carbenes are termed as nitrenes.
(2) There is probability of two spin structure for nitrenes depending upon whether the two non-bonding electrons (the normal nitrogen lone pair remains paired) comprise their spins paired or parallel.(3) generally nitrenes obey Hunds rule and the ground state triplet along with two degenerate sp-orbitals containing a single electron each.
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Pb(NO)3 + Na3Po4 --> NaNo3 + PbPO4
YES,LiAlH 4 be used to reduce nitro group to amino group in hydrogenation
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