Hybridisation and the magnetic properties of the complex, Chemistry

Assignment Help:

Q. Hybridisation and the magnetic properties of the complex?

Pauling showed that there is a direct correlation between the type of hybridisation and the magnetic properties of the complex. In order to understand this relationship, you should recapitulate the basic concepts of magnetism. The orbital motion and the spinning of the electron give rise to a certain angular momentum to an atom. This angular momentum causes the atom to acquire magnetic moment. The magnetic moment due to spin angular momentum is much greater in comparison to magnetic moment arising out of orbital angular momentum. Further, if there are two electrons in an orbital having opposite spins, the magnetic moment due to spin angular momentum will be zero. However, if there are unpaired electrons in an atom its magnetic moment is given by the expression:

395_Hybridisation and the magnetic properties of the complex.png

μ= GBM where n is the number of unpaired electrons and BBM is the unit of magnetic moment. It is called Bohr Magnetic and abbreviated as BM The formula is known as spin-only formula for the calculation of magnetic moment since in its derivation we have omitted the contribution due to orbital angular momentum.

Placed irk ail external magnetic field are pulled towards the field. Table 14.4 gives the number of unpaired electrons and the associated magnetic moment.


Related Discussions:- Hybridisation and the magnetic properties of the complex

, complete reactio

complete reaction

Acid refractory : application and examples, what are the acid refractory an...

what are the acid refractory and its application and examples?

Radioactivity, what is the principal of radiometric titration

what is the principal of radiometric titration

Dithizone-chelating agent, the reaction equations for the dissociation of d...

the reaction equations for the dissociation of dithzone into chelate anions and the formation of metal-dithizone chelates

Explain the consumer oriented product development, Consumer Oriented Produc...

Consumer Oriented Product Development It is important that new product development strategies are adjusted to identified needs in the market. This requires an appropriate met

Explain Chemical properties of f-block element, Q. Chemical Properties of f...

Q. Chemical Properties of f-block element? The lanthanides are silvery-white, highly electropositive and reactive metals. They all react slowly with cold water and quickly on h

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd