Homonuclear diatomics, Chemistry

Assignment Help:

Bonding and ant bonding orbitals

Just as an atomic orbital (AO) is the wavefunction for an electron in an atom so a molecular orbital (MO) is that for a molecule; an MO will extend over two or more atoms. Exact MOs will be calculated by solution of Schrödinger's equation for the one-electron ion but as in atoms the extension of the orbital approach to manyelectron systems involves approximations. For MOs a further approximation is made: rather than using the same but very complicated wavefunction for it is convenient to express each MO as a linear combination of AOs, the so-called LCAO approximation. This approximation have to be refined considerably for quantitative calculations on computers, but it is adequate for qualitative purposes and provides very efficient pictures of how chemical bonds form, and how they are related to the valence AOs of the atoms involved.

2469_Untitled.png

 

 

 

Fig. 1. Formation of a bonding and antibonding MO from the overlap of 1s AOs in H2

 


Related Discussions:- Homonuclear diatomics

Actinide, what are ionization energy of actinides?

what are ionization energy of actinides?

Show the properties of matter, Q. Show the Properties of Matter? Each o...

Q. Show the Properties of Matter? Each of the material the stuff around us is matter. A substance is matter which has a uniform and unchanging composition. For instance water

Illustrate uses of f-block element, Q. Illustrate Uses of f-block element? ...

Q. Illustrate Uses of f-block element? Lanthanides and many of their complexes have received wide industrial applications. For example, europium derivatives are used as phospho

Versatile nature of carbon-catenation, Versatile nature of Carbon-Catenatio...

Versatile nature of Carbon-Catenation The chemical compounds can be mainly classified into two main categories. These are organic and inorganic. More than 90 elements are in

Element have electronegativity, Two element have electronegativity of 1.2 a...

Two element have electronegativity of 1.2 and 3.0. Bond formed between them would be: (1) Ionic (2) Polar covalent ( 3) Co-ordinate (4) Metallic A ns: Ionic

Boron, why digonal relationship made

why digonal relationship made

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd