Give examples of steric effects, Chemistry

Assignment Help:

Give Examples of steric effects

These are both examples of steric effects. Placing three highly branched groups around a central boron results in van der Waals repulsions. These repulsions are severe enough that only two groups can be bound to boron in the case of disiamylborane, and only one group in the case of thexylborane. (Notice the greater number of alkyl substitutions in the "thexyl" group.) Now, alkyl branches stabilize sp2-hybridized boron (see the solution to Problem 4.48 on p. 62 of the Study Guide and Solutions Manual) just as they stabilize sp2-hybridized carbon; but if the alkyl branches are themselves branched, they form a thicket of methyl groups that interact repulsively with each other as more of these branches are accumulated. These repulsive interactions reduce the relative stability of the trialkylboranes-evidently, so much so that they cannot form.

 


Related Discussions:- Give examples of steric effects

Highest melting point, Highest melting point would be of: (1) He       ...

Highest melting point would be of: (1) He        (2) CsCl      (3)  NH 3   (4)  CHCl 3 Ans:  CsCl

What is copolymerisation, Two or more different types of monomers joined to...

Two or more different types of monomers joined together to form giant molecule is called coopolymerisation. ex--- nylon6,6      --it is a combination of hexamethylenediamine and a

Statements is not true for ionic compoundss, Which of the following stateme...

Which of the following statements is not true for ionic compoundss: (1) High melting point (2) Least lattice energy (3)Least solubility in organic compounds (4) Solubl

Substances, who created or found Styrene

who created or found Styrene

Liquification of gases, tell me about liquification of gases in detail but ...

tell me about liquification of gases in detail but in most easy words

A cyclic ester, The lactone, a cyclic ester, can form an enolate ion, and t...

The lactone, a cyclic ester, can form an enolate ion, and this ion is alkylated by methyl iodide.

Inorganic chemistry, H2O is liquid buy why H2s gas? who it is one group.

H2O is liquid buy why H2s gas? who it is one group.

What is the main obstacle in using co2 as a reactant, From the point of vie...

From the point of view of "green chemistry" - why should reactions be carried out in CO 2 instead of using carbon monoxide or phosgene (2 reasons)? Apart from the compression of c

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd