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For cations build from metals in early groups in the periodic table the complexing strength with halide ions follows the sequence
whereas with many post-transition metals and some later transition metals the reverse sequence is found (e.g. Pt2+, Hg2 +, Pb2+;). The former behavior is known as the latter as class b and class a behavior, and the difference is an example of soft and hard properties, respectively. Class b ions form rigid complexes with ligands such as ammonia, which are lighter than water, whereas class a ions do not complex with such ligands appreciably in water.
what is meant by abnormal molecular mass of solute ? discuss the factors which bring abnormality in the experimentally determined molecular masses of solutes using colligative prop
The following information is available for the extraction of Cu2+ into CCl4 with dithizone: KD,c = 7 ´ 104; b = 5 ´ 1022; Ka,HL = 3 ´ 10–5; KD,HL = 1.1 ´ 104; n = 2. What is the ex
Tetracyclines: The tetracyclines consist of hydronapht-hacene skeleton like the characteristic structural unit. The structures of tetracycline are specified as follows,
Water pressure is the same in all directions Punch holes around the base of a tall tin can with a nail. Wrap the holes as above with a strip of tape. Fill the can with water an
In solid state chemistry the CN 2 2- ion shows constitutional isomerism. The free acids of both anions (at least in the gas phase) are known. Illustrate the structural formul
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