Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Correct set of four quantum numbers for valence electron, Correct set of fo...

Correct set of four quantum numbers for valence electron of rubidium (Z = 37) is: (1)  5,0,0,+1/2                    (2)  5, 1,0,+1/2    (3)  5,1,1,+1/2

Colloides, difference between organic & inorganic colloides ?

difference between organic & inorganic colloides ?

Pauli exclusion principle, Electron configurations are governed by a limita...

Electron configurations are governed by a limitation called as the Pauli Exclusion Principle: No two electrons can have the same value for all four quantum numbers n, l, m a

Benzene, wht is the strucutre of benzene?

wht is the strucutre of benzene?

Six protons are found in the nucleus of, Six protons are found in the nucle...

Six protons are found in the nucleus of : (1) Boron              (2) Lithium     (3) Carbon  (4 )Helium Ans: Carbon

DIENES, PREPARATIONS OF DIENES

PREPARATIONS OF DIENES

Determine how many moles of compound of buffer solution, Assume that we wan...

Assume that we want to make buffer by dissolving in water some amount of the compound which we selected by the table as given below; After that adding either strong acid (f

Physical chareterstics of carbonyl compounds, Physical chareterstics of car...

Physical chareterstics of carbonyl compounds Physical state: a. Methanal is a pungent smell gas. b. Ethanal is a volatile liquid and boiling points 294 K. c. Other ald

Value of x, x grams of calcium carbonate was completely burnt in air.the we...

x grams of calcium carbonate was completely burnt in air.the weight of solid residue formed is 28 g.what is the vlue of x in grams?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd