Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Calculate the number of electrons and protons in isotope, There are 13 elec...

There are 13 electrons in an element whose nucleus comprise 14 neutrons. Obtain atomic number and atomic weight of this element. If atomic weight of the isotope of above element is

Phosphorus, PHOSPHORUS, ARSENIC AND ANTIMONY The bigger elements in the ...

PHOSPHORUS, ARSENIC AND ANTIMONY The bigger elements in the same group (15) as nitrogen are usually known as 'pnictogens' and their compounds with metals as 'pnictides'. Althoug

Pauli''s exclusion principle states that, Pauli's exclusion principle state...

Pauli's exclusion principle states that: (1) Two electrons in the same atom can have the same energy (2) Two electrons in the same atom cannot have the same spin (3) The

Number of unpaired electrons in inert gas is, Number of unpaired electrons ...

Number of unpaired electrons in inert gas is: (1) Zero         (2) 8        (3) 4                (4) 18 Ans: Zero

Explain chemistry changes of food deterioration, Chemical Changes Duri...

Chemical Changes During the processing and storage of foods, several chemical changes occur that involve the internal food components and the external environmental factors. T

Atoms are bombarded with alpha particles & out undeflected, When atoms are ...

When atoms are bombarded with alpha particles, only a few in  n, others pass out undeflected. This is because : (1) The nucleus occupies much smaller volume compared to the volu

Show reversible and exothermic reaction, Q. Show reversible and exothermic ...

Q. Show reversible and exothermic reaction? The fact that SO 2 , can be oxidised to SO 3 , by air in the presence of platinum catalyst is the basis of the contact process which

P BLOCK element, what are the electron deficient molecule explain with exam...

what are the electron deficient molecule explain with examples

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd