Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Aromatic carbonyl compounds - aldehydes and ketones, Aromatic Carbonyl Comp...

Aromatic Carbonyl Compounds - Aldehydes and Ketones Aromatic aldehydes are of two types: The compounds where - CHO group is attached directly to an aromatic ring, like benza

Solid state and quantum chemistry, What are laws of crystallography? How do...

What are laws of crystallography? How does it help in study of crystal structure?

Composition of individual phase in phase diagram–three phase, Define Compos...

Define Composition of individual phase in phase diagram–three phase? A binary system with three phases has only one degree of freedom and cannot be represented by an area on a

Determine energy level, For n= 3 energy level, the number of possible orbit...

For n= 3 energy level, the number of possible orbitals (all kinds) are: (1) 1        (2) 3         (3) 4       (4) 9 Ans: 9

Uses of oils and fats, Uses of oils and fats (a) Several oils and fats ...

Uses of oils and fats (a) Several oils and fats are used as food material. (b) Oils and fats are employed for the manufacture of glycerol, fatty acids, soaps, candles, veget

How do temperature affect electrical resistivity of metals, How do impuriti...

How do impurities and temperature affect electrical resistivity of metals? Ans: Temperature effect on resistivity: Any increase in temperature of a conductor increase

Estimate the molar mass of protein, Q. An aqueous solution of the protein b...

Q. An aqueous solution of the protein bovine serum albumin, containing 2:00 x 10 -2 g of protein per cubic centimeter, has an osmotic pressure of 8.1 x 10 -3 bar at 0 C. Estim

Stoichiometry, give 2 exaples of computatins in stoichiometry

give 2 exaples of computatins in stoichiometry

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd