Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Define the process of metallization - fabrication processes, Define the pro...

Define the process of Metallization - fabrication processes It's the process of providing electrical connections between different parts of the circuit. Aluminium is common

Name the products of hydrolysis of sucrose, Name the products of hydrolysis...

Name the products of hydrolysis of sucrose. Why is sucrose not a reducing sugar?   What are essential and non -  essential amino acids in human  food?  Give one example of each ty

Scientific notation and dimensional analysis, Q. Scientific Notation and Di...

Q. Scientific Notation and Dimensional Analysis? Very small and extremely large numbers can be compared more easily when they are converted into a form called scientific notati

Nmr, Draw C5H10O2 that has the following 1H NMR spectrum: 1.15 (t, 3 H), 1....

Draw C5H10O2 that has the following 1H NMR spectrum: 1.15 (t, 3 H), 1.25 (t, 3 H), 2.33 (q, 2 H), 4.13 (q, 2 H).

Then total possible number of subshells would be, If n+l= 6  , then total p...

If n+l= 6  , then total possible number of subshells would be: (1) 3        (2) 4        (3) 2       (4) 5 Ans:  3

Colloidal system, How many types of colloidal system? and which are they?

How many types of colloidal system? and which are they?

What is an oxidizing agent, Any chemical species that has a tendency to acc...

Any chemical species that has a tendency to accept electrons and thereby undergoing reduction themselves is known as an oxidizing agent

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd