Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Illustrate about borohydrides, Q. Illustrate about Borohydrides? Borohy...

Q. Illustrate about Borohydrides? Borohydrides like NaBH 4 ,, Be(BH 4 ,) 2 and Al(BH 4 )are the salts of complex  tetrahydridoborate anion, BH - 4 ,. Since in BH - 4 ,. bor

Separation techniquics using solute and solvent, suppose n mmol of solute A...

suppose n mmol of solute A in Vaq ml of aqueous solution is extracted with Vorg ml of animmiscible organic solvent. at equilibrium n1 mmol of A will remain in the aqueous layer and

Number of nodal centres for 2s orbital, Number of nodal centres for 2s orbi...

Number of nodal centres for 2s orbital: (1) 1        (2) 0        (3) 4        (4) 3 Ans: 1

Semicoducting polymers, mathematical expression for conductivity of polyme...

mathematical expression for conductivity of polymers

Voltametry, write a short note on cyclic voltametry

write a short note on cyclic voltametry

The angular momentum of an electron depends on, The angular momentum of an ...

The angular momentum of an electron depends on: (1) Principal quantum number (2) Azimuthal quantum number (3) Magnetic quantum number (4) All of these Ans: Azimutha

Matter, why the water is compound

why the water is compound

Gastric juice, what are the functions of gastric juice

what are the functions of gastric juice

Tautomerism - type of isomerism, Tautomerism - Type of Isomerism (i) Th...

Tautomerism - Type of Isomerism (i) The type of isomerism in which a substance exist in two readily interconvertible different structures leading to dynamic equilibrium is know

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd