Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

How to find hybridisation, how to find hybridisation?i want shortcut or any...

how to find hybridisation?i want shortcut or any trick

P block, electronic vinyas of led

electronic vinyas of led

Which of the following ions is not having the configuration, Which of the f...

Which of the following ions is not having the configuration of neon: (1) F -                      (2) Mg +2                         (3) Na +                       (4

Redox Titration, What is the reliablitiy of redox titrations?

What is the reliablitiy of redox titrations?

How to find equivalents, I put an unknown solid acid into a base solution. ...

I put an unknown solid acid into a base solution. How do I find the equivalents of base consumed?

Block diagram of atomic fluorescence spectrometry, Block diagram of atomic ...

Block diagram of atomic fluorescence spectrometry: The instrumentation for AFS consists of atom reservoir that might be a flame or a furnace etc., a basic source emitting the

Ionization energy of group, Ionization energy of group: Why does Ioniz...

Ionization energy of group: Why does Ionization energy of group IIA elements decrease from Be to Ra?  A. As the atomic size increases from Be to Ra, the attraction between

Calculate the molar volumes using molar masses, Q. This 16-part problem ill...

Q. This 16-part problem illustrates the use of experimental data from bomb calorimetry and other sources, combined with thermodynamic relations derived in this and earlier chapters

Normality, I don''t understand the concept of normality and gram equivalent...

I don''t understand the concept of normality and gram equivalent

Lipids - biomolecules, Lipids Lipids are constituents of plants and tis...

Lipids Lipids are constituents of plants and tissues that are insoluble in water although soluble in organic solvents like ether, carbon tetrachloride, chloroform, or benzene.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd