Explain the two solids and a solvent - phase diagram, Chemistry

Assignment Help:

Explain the Two solids and a solvent - Phase Diagram?

The phase diagram in Figure on the next page is for a ternary system of water and two salts with an ion in common. There is a one-phase area for solution, labeled sln; a pair of two-phase areas in which the phases are a single solid salt and the saturated solution; and a triangular three-phase area. The upper vertex of the three-phase area, the eutonic point, represents the composition of solution saturated with respect to both salts. Some representative tie lines are drawn in the two-phase areas.

1810_Two solids and a solvent.png

Figure: Ternary phase diagram for NaCl, KCl, and water at 25 C and 1 bar. The dashed lines are tie lines in the two-phase areas.

A system of three components and three phases has two degrees of freedom; at fixed values of T and p, each phase must have a fixed composition. The fixed compositions of the phases that are present when the system point falls in the three-phase area are the compositions at the three vertices of the inner triangle: solid NaCl, solid KCl, and solution of the eutonic composition xNaCl = 0.20 and xKCl = 0.11. From the position of the curved boundary that separates the one-phase solution area from the two-phase area for solution and solid KCl, we can see that adding NaCl to the saturated solution of KCl decreases the mole fraction of KCl in the saturated solution. Al- though it is not obvious in the phase diagram, adding KCl to a saturated solution of NaCl decreases the mole fraction of NaCl.


Related Discussions:- Explain the two solids and a solvent - phase diagram

Classification of dyes - ingrain dyes (developed dyes), Ingrain dyes (devel...

Ingrain dyes (developed dyes) - Ingrain dyes are those that are synthesised straight on the fabric. Instances of this type of dyes are azo dyes. In this the fabric is wrapped up

Ozone layer, if the ozone layer distroyed then earth cool why

if the ozone layer distroyed then earth cool why

Explain cohesive energy, 'Cohesive energy' : In a chemical bond, it is the...

'Cohesive energy' : In a chemical bond, it is the energy needed to dissociate a solid into isolated atoms or molecules as appropriate.

Nitration or direct method, Nitration or Direct method The number of - ...

Nitration or Direct method The number of - NO 2 groups introduced in benzene nucleus relies upon the nature and concentration of the nitrating agent, temperature of nitration

Llimitations of werners theory, Q. Llimitations of werners theory? Ther...

Q. Llimitations of werners theory? There were inherent limitations with such a simple approach. For example, the following experimental facts cannot be explained on the basis o

Lattice energy of an ionic compound, Lattice energy of an ionic compound de...

Lattice energy of an ionic compound depends upon: (1) Charge on the ion only (2) Size of the ion only (3) Packing of ions only (4) Charge on the ion and size of the io

Pure ammonia gas is injected , Ammonia is a gas for which reliable analytic...

Ammonia is a gas for which reliable analytical methods are available to explain concentration in other gases.  To measure ?ow in a 15 inch schedule 40 natural gas pipeline, pure am

Equivalent conductance of sodium acetate, When a certain cell was filled wi...

When a certain cell was filled with 0.02N KCl solution, the resistance was 350ohm when the same cell was filled with 0.01N eq solution of sodium acetate the resistance was 1158ohm.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd