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Q. Explain about Stereoisomerism?
Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometrical and optical.
Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square plana structure the two possible arrangements are shown in Fig.
In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.
This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar) and 4 (tetrahedral geometry).
Valence electron of pd Pd has ten valence electrons in the neutral atom. There are no charges and no X-type ligands in the complex; as, this is a d 10 complex.
Calculate how the internal energy stored in one O-H bond of H20 Consider the following chemical reaction H20(g)-->2H(g) + O(g) at 298.15 K and 1.00 Bar fH* [H(g)]=218.0 kJ/mole fH*
Alkanes have single bond, but why are they less reactive as compared to alkenes or alkynes which have respectively double or triple bonds ? Alkanes have only single sigma bond w
what is relative atomic mass
Explain the term Forging with diagram Forging is shaping of metal either by steady compression or impact between a hammer or ram and anvil. Related to pressing of metal or
which of the following has smallest heat of hydrogenation per mole A) 1-Butene B)trans-2-butene C)cis-2-butene D)1,3-butadiene Ans) D)1,3-
you are provided with a monobasic acid , HX with a concentration in the range of 0.5moldm-3. You arerequired to plan and carry out an experiment to determine that exact concentrati
Need help figuring out the proper steps on how to solve: What volume of 1.25M HCl in liters is needed to react completely (with nothing left over) with 0.750L of 0.200M Na2CO3? Usi
what are medicinal applications of coordination complexes
240 g of water at 20 degree C are mixed with a sample of iron at 500 degree C. The final temperature of the system is 42 degree C. Find the mass of the iron sample
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