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Q. Explain about Stereoisomerism?
Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometrical and optical.
Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square plana structure the two possible arrangements are shown in Fig.
In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.
This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar) and 4 (tetrahedral geometry).
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Which of the following configuration is correct for iron : (1) 1s 2 , 2s 2, 2p 6 , 3s 2 , 3p 6 ,, 3d 5 (2) 1s 2 , 2s 2 , 2p 6 , 3s 2 ,3p 6 , 4s 2 , 3d 5 (3)
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An isostere is: (1) NO -2 and O 3 (2) No -2 and PO 3- 4 (3) CO 2, N 2 O, NO - 3 (4)Clo - 4 and OCN - Ans: NO -2
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