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Q. Explain about Stereoisomerism?
Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometrical and optical.
Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square plana structure the two possible arrangements are shown in Fig.
In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.
This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar) and 4 (tetrahedral geometry).
Plz tell me the units of absorptivity if it has any units
1. Alcohols and amines are both nucleophilic. Explain why this reaction occurs to form Benadryl (diphenhydramine) 2. Outline a reasonable synthesis of the following:
According to Bohr's principle, the relation between principle quantum number and radius of orbit is: (1) r ∞ n (2) r ∞ n 2 (3) ∞1/n (4) r∞ 1/ n 2 Ans: r
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20.0 mL of 0.2 M CaCl 2 diluted with water to 100.0 mL. Calculate [CaCl 2 ], [Ca 2+ ] and [Cl - ]. Produce from concentrated hydrochloric acid (12 M) 3.0 L 0.60 M HCl solution.
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