Explain about stereoisomerism, Chemistry

Assignment Help:

Q. Explain about Stereoisomerism?

Stereoisomers have the same bonds but the arrangement of atoms in space is different.  Stereoisomerism can be divided into two kinds: geometrical and optical.

Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square  plana  structure   the two possible arrangements are shown in Fig.

In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.

586_Explain about Stereoisomerism.png

This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar)  and 4 (tetrahedral geometry).


Related Discussions:- Explain about stereoisomerism

Electronic configurations, what rules and principles are violated in the fo...

what rules and principles are violated in the following electronic configuration: 1s22s3

The frequency of yellow light having wavelength, The frequency of yellow li...

The frequency of yellow light having wavelength 600 nm is: (1) 5.0x10 14 Hz                 (2)  2.5 x 10 7 Hz        (3) 5.0x 10 7 Hz

Fire accident in an industry., If there is a fire accident in an industry, ...

If there is a fire accident in an industry, what  a safety enginner will do? Ans) Fire engineering is the application of engineering and science principles to protect prope

Define equilibrium with an aqueous phase, Define Equilibrium with an Aqueou...

Define Equilibrium with an Aqueous Phase? What are the values of C and F in systems consisting of solid AgCl in equilibrium with an aqueous phase containing H 2 O, Ag + (aq), C

Thermodynamics of reduction process, Q. Thermo d ynamics of Re d uction Pro...

Q. Thermo d ynamics of Re d uction Process? As you have read above, metallurgy of most metals involves reduction of their oxides. The nature of the reduction process depends up

Thermodynamics, Calculate the free energy change of following reaction at29...

Calculate the free energy change of following reaction at298 kelvin H2+I2=2HI if the enthalpy change is 51.8816kj and the entropy change is 166.15j is this reaction thermodyanamica

Explain cis- and trans-3-hexene, Explain cis- and trans-3-hexene Both ...

Explain cis- and trans-3-hexene Both cis- and trans-3-hexene should give the similar one alkyl halide product when they react with HI, and both would undergo catalytic hydroge

The electronic configuration of an element, The electronic configuration of...

The electronic configuration of an element is  1s 2 , 2s 2 2p 6 3s 2 3p 6 3d 5 4s 1 . This represents its: (1) Excited state (2) Ground state        (3)Cationic for

Chemisty, i need help finding information with the element sodium

i need help finding information with the element sodium

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd