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Q. Explain about Stereoisomerism?
Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometrical and optical.
Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square plana structure the two possible arrangements are shown in Fig.
In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.
This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar) and 4 (tetrahedral geometry).
Fractional crystallisation- Purification of organic compound The method of separation of diverse components of a mixture by repeated crystallisations is termed as fractional cr
Explain about the Galvanic Cells? An electrochemical cell is a system in which passage of an electric current through an electrical circuit is linked to an internal cell reacti
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The number of electrons in c l - ion is: (1) 19 (2) 20 (3) 18 (4) 35 Ans: 18
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Diazomethane has the following composition by mass: 28.57% c ,4.80% h and 66.64% n . The molar mass of diazometane is 42.04 g/mol. Find the molecular formula of diazomethane and dr
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Q1: The complexes of Fe +2 with 1, 10- phenanthroline has a molar absorptivity of about 11,000 L/mol cm in water at 510 nm. A 20 ml water sample thought to contain Fe +2 is mix
Q. Use the following information to draw a temperature-composition phase diagram for the binary system of H 2 O (A) and Na 2 SO 4 (B) at p = 1 bar, confining t to the range 20 to
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