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Q. Explain about Monohalides?
Monohalides of the type M2X2, (where X = F, C1 and Br) are formed only by 0. S and Se. Oxygen monofluoride decomposes above 25 K. These monohalides have got structures similar to H2, O2, having E-E bonds.
Monohalides of Te and Po are not formed because Te-Te and Po-Po bonds are not stable. The monohalides are slowly hydrolysed to give the oxoacid,
2Se2Cl2+ 2H2O -------------------> H2SeO2+ 3Se+ 4HCl
Sulphur can readily be dissolved into sulphur monochloride. S2, CI2 to give chlorosulphanp s, such as. S3 CI2 , S4,Cl2 and so on upto S100 CI2.
Q. Show Sulphide Minerals? In these minerals metals are present as their sulphides. For example, iron pyrites (FeS 2 ), calcocite (CU 2 S), chalcopyrite (CuFeS 2 ), zinc blende
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names for : A , B , C , D , E , F ,..........., X , Y , Z .
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Which one of the following is not isoelectronic with O 2- : (1) N- 3 (2) F - (3) Tl + (4) Na + Ans: Tl +
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